2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione

The crystal of the title compound, C(13)H(12)N(2)O(6), contains a bifurcated intra­molecular hydrogen bond between the N—H group and one of the O atoms from both the nitro group and the dioxane-4,6-dione moiety. In addition, mol­ecules are linked by a series of inter­molecular C—H⋯O secondary inter­...

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Detalles Bibliográficos
Autores principales: He, Yu-xin, Wu, Jin-wei, Tong, Rong-sheng, Shi, Jian-you
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089138/
https://www.ncbi.nlm.nih.gov/pubmed/21754514
http://dx.doi.org/10.1107/S1600536811014358
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author He, Yu-xin
Wu, Jin-wei
Tong, Rong-sheng
Shi, Jian-you
author_facet He, Yu-xin
Wu, Jin-wei
Tong, Rong-sheng
Shi, Jian-you
author_sort He, Yu-xin
collection PubMed
description The crystal of the title compound, C(13)H(12)N(2)O(6), contains a bifurcated intra­molecular hydrogen bond between the N—H group and one of the O atoms from both the nitro group and the dioxane-4,6-dione moiety. In addition, mol­ecules are linked by a series of inter­molecular C—H⋯O secondary inter­actions. The dihedral angles between the benzene ring and the nitro group and the conjugated part of the dioxane-4,6-dione moiety are 19.1 (2) and 17.89 (7)°, respectively.
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spelling pubmed-30891382011-07-13 2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione He, Yu-xin Wu, Jin-wei Tong, Rong-sheng Shi, Jian-you Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal of the title compound, C(13)H(12)N(2)O(6), contains a bifurcated intra­molecular hydrogen bond between the N—H group and one of the O atoms from both the nitro group and the dioxane-4,6-dione moiety. In addition, mol­ecules are linked by a series of inter­molecular C—H⋯O secondary inter­actions. The dihedral angles between the benzene ring and the nitro group and the conjugated part of the dioxane-4,6-dione moiety are 19.1 (2) and 17.89 (7)°, respectively. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089138/ /pubmed/21754514 http://dx.doi.org/10.1107/S1600536811014358 Text en © He et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Yu-xin
Wu, Jin-wei
Tong, Rong-sheng
Shi, Jian-you
2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
title 2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
title_full 2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
title_fullStr 2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
title_full_unstemmed 2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
title_short 2,2-Dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
title_sort 2,2-dimethyl-5-[(2-nitro­anilino)methyl­idene]-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089138/
https://www.ncbi.nlm.nih.gov/pubmed/21754514
http://dx.doi.org/10.1107/S1600536811014358
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AT wujinwei 22dimethyl52nitroanilinomethylidene13dioxane46dione
AT tongrongsheng 22dimethyl52nitroanilinomethylidene13dioxane46dione
AT shijianyou 22dimethyl52nitroanilinomethylidene13dioxane46dione

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