2-Chloro-1,2-diphenyl­ethanone (desyl chloride)

The title compound, C(14)H(11)ClO, is a racemic derivative of benzoin. Its carbonyl group adopts a nearly eclipsed conformation with the Cl substituent characterized by a dihedral angle of 17.5 (2)°. The closest intermolecular π–π contact is 4.258 (1) Å.

Detalles Bibliográficos
Autores principales: Betz, Richard, McCleland, Cedric, Hosten, Eric
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089139/
https://www.ncbi.nlm.nih.gov/pubmed/21754501
http://dx.doi.org/10.1107/S1600536811014541
_version_ 1782202986888429568
author Betz, Richard
McCleland, Cedric
Hosten, Eric
author_facet Betz, Richard
McCleland, Cedric
Hosten, Eric
author_sort Betz, Richard
collection PubMed
description The title compound, C(14)H(11)ClO, is a racemic derivative of benzoin. Its carbonyl group adopts a nearly eclipsed conformation with the Cl substituent characterized by a dihedral angle of 17.5 (2)°. The closest intermolecular π–π contact is 4.258 (1) Å.
format Text
id pubmed-3089139
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30891392011-07-13 2-Chloro-1,2-diphenyl­ethanone (desyl chloride) Betz, Richard McCleland, Cedric Hosten, Eric Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)ClO, is a racemic derivative of benzoin. Its carbonyl group adopts a nearly eclipsed conformation with the Cl substituent characterized by a dihedral angle of 17.5 (2)°. The closest intermolecular π–π contact is 4.258 (1) Å. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089139/ /pubmed/21754501 http://dx.doi.org/10.1107/S1600536811014541 Text en © Betz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
McCleland, Cedric
Hosten, Eric
2-Chloro-1,2-diphenyl­ethanone (desyl chloride)
title 2-Chloro-1,2-diphenyl­ethanone (desyl chloride)
title_full 2-Chloro-1,2-diphenyl­ethanone (desyl chloride)
title_fullStr 2-Chloro-1,2-diphenyl­ethanone (desyl chloride)
title_full_unstemmed 2-Chloro-1,2-diphenyl­ethanone (desyl chloride)
title_short 2-Chloro-1,2-diphenyl­ethanone (desyl chloride)
title_sort 2-chloro-1,2-diphenyl­ethanone (desyl chloride)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089139/
https://www.ncbi.nlm.nih.gov/pubmed/21754501
http://dx.doi.org/10.1107/S1600536811014541
work_keys_str_mv AT betzrichard 2chloro12diphenylethanonedesylchloride
AT mcclelandcedric 2chloro12diphenylethanonedesylchloride
AT hosteneric 2chloro12diphenylethanonedesylchloride

Ejemplares similares