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(5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2) O,O′)zinc hemihydrate
In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water molecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthylacetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-di...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089144/ https://www.ncbi.nlm.nih.gov/pubmed/21754324 http://dx.doi.org/10.1107/S1600536811013353 |
Sumario: | In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water molecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthylacetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, giving an irregular environment. In the crystal, the complex molecules are interlinked through the water molecule by O—H⋯O(carboxylate) hydrogen bonds, together with weak C—H⋯O and bipyridine ring π–π stacking interactions [ring centroid separation = 3.761 (2) Å], giving a two-dimensional network structure. |
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