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(5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2) O,O′)zinc hemihydrate
In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water molecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthylacetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-di...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089144/ https://www.ncbi.nlm.nih.gov/pubmed/21754324 http://dx.doi.org/10.1107/S1600536811013353 |
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author | Ji, Li-Li Liu, Jian-She Song, Wen-Dong |
author_facet | Ji, Li-Li Liu, Jian-She Song, Wen-Dong |
author_sort | Ji, Li-Li |
collection | PubMed |
description | In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water molecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthylacetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, giving an irregular environment. In the crystal, the complex molecules are interlinked through the water molecule by O—H⋯O(carboxylate) hydrogen bonds, together with weak C—H⋯O and bipyridine ring π–π stacking interactions [ring centroid separation = 3.761 (2) Å], giving a two-dimensional network structure. |
format | Text |
id | pubmed-3089144 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891442011-07-13 (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2) O,O′)zinc hemihydrate Ji, Li-Li Liu, Jian-She Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water molecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthylacetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, giving an irregular environment. In the crystal, the complex molecules are interlinked through the water molecule by O—H⋯O(carboxylate) hydrogen bonds, together with weak C—H⋯O and bipyridine ring π–π stacking interactions [ring centroid separation = 3.761 (2) Å], giving a two-dimensional network structure. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089144/ /pubmed/21754324 http://dx.doi.org/10.1107/S1600536811013353 Text en © Ji et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ji, Li-Li Liu, Jian-She Song, Wen-Dong (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2) O,O′)zinc hemihydrate |
title | (5,5′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2)
O,O′)zinc hemihydrate |
title_full | (5,5′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2)
O,O′)zinc hemihydrate |
title_fullStr | (5,5′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2)
O,O′)zinc hemihydrate |
title_full_unstemmed | (5,5′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2)
O,O′)zinc hemihydrate |
title_short | (5,5′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ(2)
O,O′)zinc hemihydrate |
title_sort | (5,5′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)(1-naphthylacetato-κo)(1-naphthylacetato-κ(2)
o,o′)zinc hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089144/ https://www.ncbi.nlm.nih.gov/pubmed/21754324 http://dx.doi.org/10.1107/S1600536811013353 |
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