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(5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate

In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water mol­ecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthyl­acetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-di...

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Detalles Bibliográficos
Autores principales: Ji, Li-Li, Liu, Jian-She, Song, Wen-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089144/
https://www.ncbi.nlm.nih.gov/pubmed/21754324
http://dx.doi.org/10.1107/S1600536811013353
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author Ji, Li-Li
Liu, Jian-She
Song, Wen-Dong
author_facet Ji, Li-Li
Liu, Jian-She
Song, Wen-Dong
author_sort Ji, Li-Li
collection PubMed
description In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water mol­ecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthyl­acetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, giving an irregular environment. In the crystal, the complex mol­ecules are inter­linked through the water mol­ecule by O—H⋯O(carboxyl­ate) hydrogen bonds, together with weak C—H⋯O and bipyridine ring π–π stacking inter­actions [ring centroid separation = 3.761 (2) Å], giving a two-dimensional network structure.
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spelling pubmed-30891442011-07-13 (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate Ji, Li-Li Liu, Jian-She Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(12)H(9)O(2))(2)(C(12)H(12)N(2))]·0.5H(2)O, the water mol­ecule lies on a twofold rotation axis. The Zn(II) atom is coordinated by three O atoms from two 1-naphthyl­acetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, giving an irregular environment. In the crystal, the complex mol­ecules are inter­linked through the water mol­ecule by O—H⋯O(carboxyl­ate) hydrogen bonds, together with weak C—H⋯O and bipyridine ring π–π stacking inter­actions [ring centroid separation = 3.761 (2) Å], giving a two-dimensional network structure. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089144/ /pubmed/21754324 http://dx.doi.org/10.1107/S1600536811013353 Text en © Ji et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ji, Li-Li
Liu, Jian-She
Song, Wen-Dong
(5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate
title (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate
title_full (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate
title_fullStr (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate
title_full_unstemmed (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate
title_short (5,5′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(1-naphthyl­acetato-κO)(1-naphthyl­acetato-κ(2) O,O′)zinc hemihydrate
title_sort (5,5′-dimethyl-2,2′-bipyridine-κ(2) n,n′)(1-naphthyl­acetato-κo)(1-naphthyl­acetato-κ(2) o,o′)zinc hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089144/
https://www.ncbi.nlm.nih.gov/pubmed/21754324
http://dx.doi.org/10.1107/S1600536811013353
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