Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)

Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic–organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the ino...

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Detalles Bibliográficos
Autores principales: Oh, In-Hwan, Kim, Dahye, Huh, Young-Duk, Park, Younbong, Park, J. M. Sungil, Park, Seong-Hun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089155/
https://www.ncbi.nlm.nih.gov/pubmed/21754265
http://dx.doi.org/10.1107/S1600536811011603
Descripción
Sumario:Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic–organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N—H⋯Cl hydrogen bonds. The CoCl(4) tetra­hedra connect to the cations through N—H⋯Cl hydrogen bonds, building a two-dimensional network extending parallel to (010).

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