Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)

Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic–organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the ino...

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Detalles Bibliográficos
Autores principales: Oh, In-Hwan, Kim, Dahye, Huh, Young-Duk, Park, Younbong, Park, J. M. Sungil, Park, Seong-Hun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089155/
https://www.ncbi.nlm.nih.gov/pubmed/21754265
http://dx.doi.org/10.1107/S1600536811011603
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author Oh, In-Hwan
Kim, Dahye
Huh, Young-Duk
Park, Younbong
Park, J. M. Sungil
Park, Seong-Hun
author_facet Oh, In-Hwan
Kim, Dahye
Huh, Young-Duk
Park, Younbong
Park, J. M. Sungil
Park, Seong-Hun
author_sort Oh, In-Hwan
collection PubMed
description Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic–organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N—H⋯Cl hydrogen bonds. The CoCl(4) tetra­hedra connect to the cations through N—H⋯Cl hydrogen bonds, building a two-dimensional network extending parallel to (010).
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spelling pubmed-30891552011-07-13 Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II) Oh, In-Hwan Kim, Dahye Huh, Young-Duk Park, Younbong Park, J. M. Sungil Park, Seong-Hun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic–organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N—H⋯Cl hydrogen bonds. The CoCl(4) tetra­hedra connect to the cations through N—H⋯Cl hydrogen bonds, building a two-dimensional network extending parallel to (010). International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089155/ /pubmed/21754265 http://dx.doi.org/10.1107/S1600536811011603 Text en © Oh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oh, In-Hwan
Kim, Dahye
Huh, Young-Duk
Park, Younbong
Park, J. M. Sungil
Park, Seong-Hun
Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)
title Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)
title_full Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)
title_fullStr Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)
title_full_unstemmed Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)
title_short Bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(II)
title_sort bis(2-phenyl­ethyl­ammonium) tetra­chloridocobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089155/
https://www.ncbi.nlm.nih.gov/pubmed/21754265
http://dx.doi.org/10.1107/S1600536811011603
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AT parkyounbong bis2phenylethylammoniumtetrachloridocobaltateii
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AT parkseonghun bis2phenylethylammoniumtetrachloridocobaltateii

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