catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]

In the polymeric title complex, [Mn(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), the Mn(2+) cation and the 4,4′-bipyridine ligand lie on a twofold rotation axis. The cation has an MnN(2)O(4) octa­hedral environment, being coordinated by the O atoms of two water mol­ecules and two monodentate (4-t...

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Detalles Bibliográficos
Autor principal: Zheng, Xiao-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089158/
https://www.ncbi.nlm.nih.gov/pubmed/21754266
http://dx.doi.org/10.1107/S1600536811011263
Descripción
Sumario:In the polymeric title complex, [Mn(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), the Mn(2+) cation and the 4,4′-bipyridine ligand lie on a twofold rotation axis. The cation has an MnN(2)O(4) octa­hedral environment, being coordinated by the O atoms of two water mol­ecules and two monodentate (4-tolyl­sulfan­yl)acetate anions, and by two N atoms of two 4,4′-bipyridine ligands. The latter bridge adjacent cations into linear chains parallel to [010]. The chains are further linked with each other into a two-dimensional network parallel to (100) via inter­molecular O—H⋯O hydrogen bonds.

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