catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]

In the polymeric title complex, [Mn(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), the Mn(2+) cation and the 4,4′-bipyridine ligand lie on a twofold rotation axis. The cation has an MnN(2)O(4) octa­hedral environment, being coordinated by the O atoms of two water mol­ecules and two monodentate (4-t...

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Detalles Bibliográficos
Autor principal: Zheng, Xiao-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089158/
https://www.ncbi.nlm.nih.gov/pubmed/21754266
http://dx.doi.org/10.1107/S1600536811011263
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author Zheng, Xiao-Yong
author_facet Zheng, Xiao-Yong
author_sort Zheng, Xiao-Yong
collection PubMed
description In the polymeric title complex, [Mn(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), the Mn(2+) cation and the 4,4′-bipyridine ligand lie on a twofold rotation axis. The cation has an MnN(2)O(4) octa­hedral environment, being coordinated by the O atoms of two water mol­ecules and two monodentate (4-tolyl­sulfan­yl)acetate anions, and by two N atoms of two 4,4′-bipyridine ligands. The latter bridge adjacent cations into linear chains parallel to [010]. The chains are further linked with each other into a two-dimensional network parallel to (100) via inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-30891582011-07-13 catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′] Zheng, Xiao-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [Mn(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), the Mn(2+) cation and the 4,4′-bipyridine ligand lie on a twofold rotation axis. The cation has an MnN(2)O(4) octa­hedral environment, being coordinated by the O atoms of two water mol­ecules and two monodentate (4-tolyl­sulfan­yl)acetate anions, and by two N atoms of two 4,4′-bipyridine ligands. The latter bridge adjacent cations into linear chains parallel to [010]. The chains are further linked with each other into a two-dimensional network parallel to (100) via inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089158/ /pubmed/21754266 http://dx.doi.org/10.1107/S1600536811011263 Text en © Xiao-Yong Zheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Xiao-Yong
catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_fullStr catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_short catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_sort catena-poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κo]manganese(ii)]-μ-4,4′-bipyridine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089158/
https://www.ncbi.nlm.nih.gov/pubmed/21754266
http://dx.doi.org/10.1107/S1600536811011263
work_keys_str_mv AT zhengxiaoyong catenapolydiaquabis24tolylsulfanylacetatokomanganeseiim44bipyridinek2nn

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