3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide

In the title mol­ecule, C(22)H(13)Br(2)NO(2), the three benzene rings are arranged in a propeller-like fashion around the central malemide ring, making dihedral angles of 48.2 (4), 30.2 (4) and 34.8 (4)° with the malemide ring. The C—C single-bond lengths connecting benzene groups and maleimide are...

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Detalles Bibliográficos
Autores principales: Liu, Yong, Zheng, Shuai, Zhou, Jing, Gao, Dongmei, Du, Zhen-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089159/
https://www.ncbi.nlm.nih.gov/pubmed/21754500
http://dx.doi.org/10.1107/S1600536811014152
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author Liu, Yong
Zheng, Shuai
Zhou, Jing
Gao, Dongmei
Du, Zhen-Ting
author_facet Liu, Yong
Zheng, Shuai
Zhou, Jing
Gao, Dongmei
Du, Zhen-Ting
author_sort Liu, Yong
collection PubMed
description In the title mol­ecule, C(22)H(13)Br(2)NO(2), the three benzene rings are arranged in a propeller-like fashion around the central malemide ring, making dihedral angles of 48.2 (4), 30.2 (4) and 34.8 (4)° with the malemide ring. The C—C single-bond lengths connecting benzene groups and maleimide are significantly shorter [C—C = 1.468 (9) and 1.478 (9) Å] than a typical Csp (3)—Csp (3) single bond, indicating partial conjugation between the benzene and the mal­eimide. A weak non­classical C—H⋯O hydrogen bond helps to stabilize the crystal structure.
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spelling pubmed-30891592011-07-13 3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide Liu, Yong Zheng, Shuai Zhou, Jing Gao, Dongmei Du, Zhen-Ting Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(22)H(13)Br(2)NO(2), the three benzene rings are arranged in a propeller-like fashion around the central malemide ring, making dihedral angles of 48.2 (4), 30.2 (4) and 34.8 (4)° with the malemide ring. The C—C single-bond lengths connecting benzene groups and maleimide are significantly shorter [C—C = 1.468 (9) and 1.478 (9) Å] than a typical Csp (3)—Csp (3) single bond, indicating partial conjugation between the benzene and the mal­eimide. A weak non­classical C—H⋯O hydrogen bond helps to stabilize the crystal structure. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089159/ /pubmed/21754500 http://dx.doi.org/10.1107/S1600536811014152 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Yong
Zheng, Shuai
Zhou, Jing
Gao, Dongmei
Du, Zhen-Ting
3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
title 3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
title_full 3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
title_fullStr 3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
title_full_unstemmed 3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
title_short 3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
title_sort 3,4-bis(4-bromo­phen­yl)-n-phenyl­maleimide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089159/
https://www.ncbi.nlm.nih.gov/pubmed/21754500
http://dx.doi.org/10.1107/S1600536811014152
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AT zhengshuai 34bis4bromophenylnphenylmaleimide
AT zhoujing 34bis4bromophenylnphenylmaleimide
AT gaodongmei 34bis4bromophenylnphenylmaleimide
AT duzhenting 34bis4bromophenylnphenylmaleimide

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