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Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone
In the title compound, C(22)H(17)NO(3)S, the N atom of the indole ring system deviates by 0.031 (3) Å from a least-squares plane fitted through all nine non-H ring atoms. The geometry around the S atom can be described as distorted tetrahedral. As a result of the electron-withdrawing character of t...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089169/ https://www.ncbi.nlm.nih.gov/pubmed/21754535 http://dx.doi.org/10.1107/S1600536811014826 |
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author | Ranjith, S. SubbiahPandi, A. Dhayalan, V. MohanaKrishnan, A. K. |
author_facet | Ranjith, S. SubbiahPandi, A. Dhayalan, V. MohanaKrishnan, A. K. |
author_sort | Ranjith, S. |
collection | PubMed |
description | In the title compound, C(22)H(17)NO(3)S, the N atom of the indole ring system deviates by 0.031 (3) Å from a least-squares plane fitted through all nine non-H ring atoms. The geometry around the S atom can be described as distorted tetrahedral. As a result of the electron-withdrawing character of the phenylsulfonyl groups, the N—Csp (2) bond lengths are longer than the typical mean value for N atoms with a planar configuration. |
format | Text |
id | pubmed-3089169 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891692011-07-13 Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone Ranjith, S. SubbiahPandi, A. Dhayalan, V. MohanaKrishnan, A. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(17)NO(3)S, the N atom of the indole ring system deviates by 0.031 (3) Å from a least-squares plane fitted through all nine non-H ring atoms. The geometry around the S atom can be described as distorted tetrahedral. As a result of the electron-withdrawing character of the phenylsulfonyl groups, the N—Csp (2) bond lengths are longer than the typical mean value for N atoms with a planar configuration. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089169/ /pubmed/21754535 http://dx.doi.org/10.1107/S1600536811014826 Text en © Ranjith et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ranjith, S. SubbiahPandi, A. Dhayalan, V. MohanaKrishnan, A. K. Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone |
title | Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone |
title_full | Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone |
title_fullStr | Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone |
title_full_unstemmed | Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone |
title_short | Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone |
title_sort | phenyl(3-methyl-1-phenylsulfonyl-1h-indol-2-yl)methanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089169/ https://www.ncbi.nlm.nih.gov/pubmed/21754535 http://dx.doi.org/10.1107/S1600536811014826 |
work_keys_str_mv | AT ranjiths phenyl3methyl1phenylsulfonyl1hindol2ylmethanone AT subbiahpandia phenyl3methyl1phenylsulfonyl1hindol2ylmethanone AT dhayalanv phenyl3methyl1phenylsulfonyl1hindol2ylmethanone AT mohanakrishnanak phenyl3methyl1phenylsulfonyl1hindol2ylmethanone |