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(E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one
In the title compound, C(20)H(15)N(3)O(3)S, the thiazole ring is approximately planar, with a maximum deviation of 0.003 (1) Å, and makes dihedral angles of 7.44 (6) and 1.88 (6)° with the hydroxy-substituted phenyl ring and the pyran ring, respectively. The hydroxyl group is disordered over two s...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089171/ https://www.ncbi.nlm.nih.gov/pubmed/21754396 http://dx.doi.org/10.1107/S1600536811012189 |
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author | Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Arshad, Afsheen |
collection | PubMed |
description | In the title compound, C(20)H(15)N(3)O(3)S, the thiazole ring is approximately planar, with a maximum deviation of 0.003 (1) Å, and makes dihedral angles of 7.44 (6) and 1.88 (6)° with the hydroxy-substituted phenyl ring and the pyran ring, respectively. The hydroxyl group is disordered over two sets of sites, with an occupancy ratio of 0.567 (3):0.433 (3). In the crystal, the major disorder component molecules are connected via bifurcated (three-centre) O—H⋯O and C—H⋯O hydrogen bonds, generating R (1) (2)(6) motifs and resulting in supramolecular chains along the a axis. In the minor occupancy component, however, molecules are connected via C—H⋯O hydrogen bonds, forming supramolecular chains along the b axis. Furthermore, the crystal structure is stabilized by π–π interactions between the thiazole rings [centroid–centroid distance = 3.5476 (7) Å]. |
format | Text |
id | pubmed-3089171 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891712011-07-13 (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)N(3)O(3)S, the thiazole ring is approximately planar, with a maximum deviation of 0.003 (1) Å, and makes dihedral angles of 7.44 (6) and 1.88 (6)° with the hydroxy-substituted phenyl ring and the pyran ring, respectively. The hydroxyl group is disordered over two sets of sites, with an occupancy ratio of 0.567 (3):0.433 (3). In the crystal, the major disorder component molecules are connected via bifurcated (three-centre) O—H⋯O and C—H⋯O hydrogen bonds, generating R (1) (2)(6) motifs and resulting in supramolecular chains along the a axis. In the minor occupancy component, however, molecules are connected via C—H⋯O hydrogen bonds, forming supramolecular chains along the b axis. Furthermore, the crystal structure is stabilized by π–π interactions between the thiazole rings [centroid–centroid distance = 3.5476 (7) Å]. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089171/ /pubmed/21754396 http://dx.doi.org/10.1107/S1600536811012189 Text en © Arshad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title | (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_full | (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_fullStr | (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_full_unstemmed | (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_short | (E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_sort | (e)-3-(2-{2-[1-(3-hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089171/ https://www.ncbi.nlm.nih.gov/pubmed/21754396 http://dx.doi.org/10.1107/S1600536811012189 |
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