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(2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione
The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis(2-acetylphenoxy)-3-oxapentane with bis(2-formylphenoxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethylene frag...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089172/ https://www.ncbi.nlm.nih.gov/pubmed/21754440 http://dx.doi.org/10.1107/S1600536811013201 |
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author | Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. |
author_facet | Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. |
author_sort | Anh, Le Tuan |
collection | PubMed |
description | The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis(2-acetylphenoxy)-3-oxapentane with bis(2-formylphenoxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethylene fragments have E configurations. The volume of the internal cavity of the macrocycle is approximately 125 Å(3). In the crystal, the molecules are arranged at van der Waals distances. |
format | Text |
id | pubmed-3089172 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891722011-07-13 (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis(2-acetylphenoxy)-3-oxapentane with bis(2-formylphenoxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethylene fragments have E configurations. The volume of the internal cavity of the macrocycle is approximately 125 Å(3). In the crystal, the molecules are arranged at van der Waals distances. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089172/ /pubmed/21754440 http://dx.doi.org/10.1107/S1600536811013201 Text en © Anh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
title | (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
title_full | (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
title_fullStr | (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
title_full_unstemmed | (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
title_short | (2E,25E)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
title_sort | (2e,25e)-11,14,17,33,36,39,42-heptaoxapentacyclo[41.4.0.0(5,10).0(18,23).0(27,32)]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089172/ https://www.ncbi.nlm.nih.gov/pubmed/21754440 http://dx.doi.org/10.1107/S1600536811013201 |
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