(2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione

The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis­(2-acetyl­phen­oxy)-3-oxapentane with bis­(2-formyl­phen­oxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethyl­ene frag...

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Detalles Bibliográficos
Autores principales: Anh, Le Tuan, Hieu, Truong Hong, Soldatenkov, Anatoly T., Soldatova, Svetlana A., Khrustalev, Victor N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089172/
https://www.ncbi.nlm.nih.gov/pubmed/21754440
http://dx.doi.org/10.1107/S1600536811013201
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author Anh, Le Tuan
Hieu, Truong Hong
Soldatenkov, Anatoly T.
Soldatova, Svetlana A.
Khrustalev, Victor N.
author_facet Anh, Le Tuan
Hieu, Truong Hong
Soldatenkov, Anatoly T.
Soldatova, Svetlana A.
Khrustalev, Victor N.
author_sort Anh, Le Tuan
collection PubMed
description The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis­(2-acetyl­phen­oxy)-3-oxapentane with bis­(2-formyl­phen­oxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethyl­ene fragments have E configurations. The volume of the inter­nal cavity of the macrocycle is approximately 125 Å(3). In the crystal, the mol­ecules are arranged at van der Waals distances.
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spelling pubmed-30891722011-07-13 (2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis­(2-acetyl­phen­oxy)-3-oxapentane with bis­(2-formyl­phen­oxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethyl­ene fragments have E configurations. The volume of the inter­nal cavity of the macrocycle is approximately 125 Å(3). In the crystal, the mol­ecules are arranged at van der Waals distances. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089172/ /pubmed/21754440 http://dx.doi.org/10.1107/S1600536811013201 Text en © Anh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anh, Le Tuan
Hieu, Truong Hong
Soldatenkov, Anatoly T.
Soldatova, Svetlana A.
Khrustalev, Victor N.
(2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
title (2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
title_full (2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
title_fullStr (2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
title_full_unstemmed (2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
title_short (2E,25E)-11,14,17,33,36,39,42-Hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
title_sort (2e,25e)-11,14,17,33,36,39,42-hepta­oxa­penta­cyclo­[41.4.0.0(5,10).0(18,23).0(27,32)]hepta­tetra­conta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetra­decaene-4,24-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089172/
https://www.ncbi.nlm.nih.gov/pubmed/21754440
http://dx.doi.org/10.1107/S1600536811013201
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