Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]

In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two a...

Descripción completa

Detalles Bibliográficos
Autores principales: Seo, Daniel M., Boyle, Paul D., Henderson, Wesley A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089180/
https://www.ncbi.nlm.nih.gov/pubmed/21754274
http://dx.doi.org/10.1107/S1600536811011561
Descripción
Sumario:In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile mol­ecules in a tetra­hedral geometry.

Ejemplares similares