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Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]

In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two a...

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Detalles Bibliográficos
Autores principales: Seo, Daniel M., Boyle, Paul D., Henderson, Wesley A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089180/
https://www.ncbi.nlm.nih.gov/pubmed/21754274
http://dx.doi.org/10.1107/S1600536811011561
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author Seo, Daniel M.
Boyle, Paul D.
Henderson, Wesley A.
author_facet Seo, Daniel M.
Boyle, Paul D.
Henderson, Wesley A.
author_sort Seo, Daniel M.
collection PubMed
description In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile mol­ecules in a tetra­hedral geometry.
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spelling pubmed-30891802011-07-13 Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium] Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile mol­ecules in a tetra­hedral geometry. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089180/ /pubmed/21754274 http://dx.doi.org/10.1107/S1600536811011561 Text en © Seo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seo, Daniel M.
Boyle, Paul D.
Henderson, Wesley A.
Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]
title Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]
title_full Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]
title_fullStr Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]
title_full_unstemmed Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]
title_short Poly[bis­(acetonitrile-κN)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) O,O′:O′′:O′′′]dilithium]
title_sort poly[bis­(acetonitrile-κn)bis­[μ(3)-bis(tri­fluoro­methane­sulfonyl)­imido-κ(4) o,o′:o′′:o′′′]dilithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089180/
https://www.ncbi.nlm.nih.gov/pubmed/21754274
http://dx.doi.org/10.1107/S1600536811011561
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