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Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4) O,O′:O′′:O′′′]dilithium]
In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two a...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089180/ https://www.ncbi.nlm.nih.gov/pubmed/21754274 http://dx.doi.org/10.1107/S1600536811011561 |
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author | Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. |
author_facet | Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. |
author_sort | Seo, Daniel M. |
collection | PubMed |
description | In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile molecules in a tetrahedral geometry. |
format | Text |
id | pubmed-3089180 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891802011-07-13 Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4) O,O′:O′′:O′′′]dilithium] Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(−)) anions. The third Li(+) cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile molecules in a tetrahedral geometry. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089180/ /pubmed/21754274 http://dx.doi.org/10.1107/S1600536811011561 Text en © Seo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4) O,O′:O′′:O′′′]dilithium] |
title | Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4)
O,O′:O′′:O′′′]dilithium] |
title_full | Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4)
O,O′:O′′:O′′′]dilithium] |
title_fullStr | Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4)
O,O′:O′′:O′′′]dilithium] |
title_full_unstemmed | Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4)
O,O′:O′′:O′′′]dilithium] |
title_short | Poly[bis(acetonitrile-κN)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4)
O,O′:O′′:O′′′]dilithium] |
title_sort | poly[bis(acetonitrile-κn)bis[μ(3)-bis(trifluoromethanesulfonyl)imido-κ(4)
o,o′:o′′:o′′′]dilithium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089180/ https://www.ncbi.nlm.nih.gov/pubmed/21754274 http://dx.doi.org/10.1107/S1600536811011561 |
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