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(E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine

In the title compound, C(13)H(9)FN(4)O(4), the dihedral angle between the mean planes of the two benzene rings of the nearly planar mol­ecule is 6.6 (9)°. The dihedral angles between the mean planes of the benzene ring and its two attached nitro groups are 6.7 (7) and 7.2 (9)°. Crystal packing is st...

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Autores principales: Jasinski, Jerry P., Braley, Adam N., Chidan Kumar, C. S., Yathirajan, H. S., Mayekar, A. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089184/
https://www.ncbi.nlm.nih.gov/pubmed/21754502
http://dx.doi.org/10.1107/S1600536811014383
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author Jasinski, Jerry P.
Braley, Adam N.
Chidan Kumar, C. S.
Yathirajan, H. S.
Mayekar, A. N.
author_facet Jasinski, Jerry P.
Braley, Adam N.
Chidan Kumar, C. S.
Yathirajan, H. S.
Mayekar, A. N.
author_sort Jasinski, Jerry P.
collection PubMed
description In the title compound, C(13)H(9)FN(4)O(4), the dihedral angle between the mean planes of the two benzene rings of the nearly planar mol­ecule is 6.6 (9)°. The dihedral angles between the mean planes of the benzene ring and its two attached nitro groups are 6.7 (7) and 7.2 (9)°. Crystal packing is stabilized by N—H⋯O hydrogen bonds, weak C—H⋯O and C—H⋯F inter­molecular inter­actions and centroid–centroid π-ring stacking inter­actions.
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spelling pubmed-30891842011-07-13 (E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine Jasinski, Jerry P. Braley, Adam N. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(9)FN(4)O(4), the dihedral angle between the mean planes of the two benzene rings of the nearly planar mol­ecule is 6.6 (9)°. The dihedral angles between the mean planes of the benzene ring and its two attached nitro groups are 6.7 (7) and 7.2 (9)°. Crystal packing is stabilized by N—H⋯O hydrogen bonds, weak C—H⋯O and C—H⋯F inter­molecular inter­actions and centroid–centroid π-ring stacking inter­actions. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089184/ /pubmed/21754502 http://dx.doi.org/10.1107/S1600536811014383 Text en © Jasinski et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jasinski, Jerry P.
Braley, Adam N.
Chidan Kumar, C. S.
Yathirajan, H. S.
Mayekar, A. N.
(E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
title (E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
title_full (E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
title_fullStr (E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
title_full_unstemmed (E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
title_short (E)-1-(2,4-Dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
title_sort (e)-1-(2,4-dinitro­phen­yl)-2-(2-fluoro­benzyl­idene)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089184/
https://www.ncbi.nlm.nih.gov/pubmed/21754502
http://dx.doi.org/10.1107/S1600536811014383
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