Cargando…
(E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine
In the title compound, C(13)H(9)FN(4)O(4), the dihedral angle between the mean planes of the two benzene rings of the nearly planar molecule is 6.6 (9)°. The dihedral angles between the mean planes of the benzene ring and its two attached nitro groups are 6.7 (7) and 7.2 (9)°. Crystal packing is st...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089184/ https://www.ncbi.nlm.nih.gov/pubmed/21754502 http://dx.doi.org/10.1107/S1600536811014383 |
_version_ | 1782202997530427392 |
---|---|
author | Jasinski, Jerry P. Braley, Adam N. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. |
author_facet | Jasinski, Jerry P. Braley, Adam N. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. |
author_sort | Jasinski, Jerry P. |
collection | PubMed |
description | In the title compound, C(13)H(9)FN(4)O(4), the dihedral angle between the mean planes of the two benzene rings of the nearly planar molecule is 6.6 (9)°. The dihedral angles between the mean planes of the benzene ring and its two attached nitro groups are 6.7 (7) and 7.2 (9)°. Crystal packing is stabilized by N—H⋯O hydrogen bonds, weak C—H⋯O and C—H⋯F intermolecular interactions and centroid–centroid π-ring stacking interactions. |
format | Text |
id | pubmed-3089184 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891842011-07-13 (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine Jasinski, Jerry P. Braley, Adam N. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(9)FN(4)O(4), the dihedral angle between the mean planes of the two benzene rings of the nearly planar molecule is 6.6 (9)°. The dihedral angles between the mean planes of the benzene ring and its two attached nitro groups are 6.7 (7) and 7.2 (9)°. Crystal packing is stabilized by N—H⋯O hydrogen bonds, weak C—H⋯O and C—H⋯F intermolecular interactions and centroid–centroid π-ring stacking interactions. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089184/ /pubmed/21754502 http://dx.doi.org/10.1107/S1600536811014383 Text en © Jasinski et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jasinski, Jerry P. Braley, Adam N. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
title | (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
title_full | (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
title_fullStr | (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
title_full_unstemmed | (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
title_short | (E)-1-(2,4-Dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
title_sort | (e)-1-(2,4-dinitrophenyl)-2-(2-fluorobenzylidene)hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089184/ https://www.ncbi.nlm.nih.gov/pubmed/21754502 http://dx.doi.org/10.1107/S1600536811014383 |
work_keys_str_mv | AT jasinskijerryp e124dinitrophenyl22fluorobenzylidenehydrazine AT braleyadamn e124dinitrophenyl22fluorobenzylidenehydrazine AT chidankumarcs e124dinitrophenyl22fluorobenzylidenehydrazine AT yathirajanhs e124dinitrophenyl22fluorobenzylidenehydrazine AT mayekaran e124dinitrophenyl22fluorobenzylidenehydrazine |