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(Acetylacetonato-κ(2) O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3) N,N′,O)oxidovanadium(IV)
The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetylacetonate anion, forming a distorted cis-VN(2)O(4)...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089186/ https://www.ncbi.nlm.nih.gov/pubmed/21754355 http://dx.doi.org/10.1107/S1600536811015406 |
| _version_ | 1782202998014869504 |
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| author | Wang, Fu-Ming |
| author_facet | Wang, Fu-Ming |
| author_sort | Wang, Fu-Ming |
| collection | PubMed |
| description | The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetylacetonate anion, forming a distorted cis-VN(2)O(4) octahedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetylacetone ligand towards the oxide O atom is 0.256 (2) Å. |
| format | Text |
| id | pubmed-3089186 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30891862011-07-13 (Acetylacetonato-κ(2) O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3) N,N′,O)oxidovanadium(IV) Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetylacetonate anion, forming a distorted cis-VN(2)O(4) octahedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetylacetone ligand towards the oxide O atom is 0.256 (2) Å. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089186/ /pubmed/21754355 http://dx.doi.org/10.1107/S1600536811015406 Text en © Fu-Ming Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Fu-Ming (Acetylacetonato-κ(2) O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3) N,N′,O)oxidovanadium(IV) |
| title | (Acetylacetonato-κ(2)
O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O)oxidovanadium(IV) |
| title_full | (Acetylacetonato-κ(2)
O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O)oxidovanadium(IV) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O)oxidovanadium(IV) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O)oxidovanadium(IV) |
| title_short | (Acetylacetonato-κ(2)
O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O)oxidovanadium(IV) |
| title_sort | (acetylacetonato-κ(2)
o,o′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ(3)
n,n′,o)oxidovanadium(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089186/ https://www.ncbi.nlm.nih.gov/pubmed/21754355 http://dx.doi.org/10.1107/S1600536811015406 |
| work_keys_str_mv | AT wangfuming acetylacetonatok2oo2bromo4chloro62dimethylaminoethyliminomethylphenolatok3nnooxidovanadiumiv |