Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate

The title compound, Li(+)·C(2)BF(2)O(4) (−)·2C(4)H(8)O(2)S, is a dimeric species, which resides across a crystallographic inversion center. The dimers form eight-membered rings containing two Li(+) cations, which are joined by O(2)S sulfone linkages. The Li(+) cations are ligated by four O atoms fro...

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Detalles Bibliográficos
Autores principales: Allen, Joshua L., Boyle, Paul D., Henderson, Wesley A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089187/
https://www.ncbi.nlm.nih.gov/pubmed/21754273
http://dx.doi.org/10.1107/S1600536811011743
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author Allen, Joshua L.
Boyle, Paul D.
Henderson, Wesley A.
author_facet Allen, Joshua L.
Boyle, Paul D.
Henderson, Wesley A.
author_sort Allen, Joshua L.
collection PubMed
description The title compound, Li(+)·C(2)BF(2)O(4) (−)·2C(4)H(8)O(2)S, is a dimeric species, which resides across a crystallographic inversion center. The dimers form eight-membered rings containing two Li(+) cations, which are joined by O(2)S sulfone linkages. The Li(+) cations are ligated by four O atoms from the anions and solvent mol­ecules, forming a pseudo-tetra­hedral geometry. The exocyclic coordination sites are occupied by O atoms from the oxalate group of the difluoro­(oxalato)borate anion and an additional tetra­methyl­ene sulfone ligand.
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spelling pubmed-30891872011-07-13 Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate Allen, Joshua L. Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, Li(+)·C(2)BF(2)O(4) (−)·2C(4)H(8)O(2)S, is a dimeric species, which resides across a crystallographic inversion center. The dimers form eight-membered rings containing two Li(+) cations, which are joined by O(2)S sulfone linkages. The Li(+) cations are ligated by four O atoms from the anions and solvent mol­ecules, forming a pseudo-tetra­hedral geometry. The exocyclic coordination sites are occupied by O atoms from the oxalate group of the difluoro­(oxalato)borate anion and an additional tetra­methyl­ene sulfone ligand. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089187/ /pubmed/21754273 http://dx.doi.org/10.1107/S1600536811011743 Text en © Allen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Allen, Joshua L.
Boyle, Paul D.
Henderson, Wesley A.
Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
title Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
title_full Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
title_fullStr Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
title_full_unstemmed Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
title_short Lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
title_sort lithium difluoro­(oxalato)borate tetra­methyl­ene sulfone disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089187/
https://www.ncbi.nlm.nih.gov/pubmed/21754273
http://dx.doi.org/10.1107/S1600536811011743
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AT boylepauld lithiumdifluorooxalatoboratetetramethylenesulfonedisolvate
AT hendersonwesleya lithiumdifluorooxalatoboratetetramethylenesulfonedisolvate

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