Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate

The title manganese(II) substituted gallophosphate, K(0.5)Rb(0.5)[Ga(2)Mn(PO(4))(3)(H(2)O)(2)], features a three-dimensional network built of PO(4) tetra­hedra, GaO(5) trigonal bipyramids and MnO(6) octa­hedra. The Rb(I) and K(I) ions, which are disordered with respect to each other in a 1:1 ratio,...

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Detalles Bibliográficos
Autores principales: Zhang, Jing, Li, Ping, Liu, Zhi-Hong, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089190/
https://www.ncbi.nlm.nih.gov/pubmed/21754256
http://dx.doi.org/10.1107/S160053681101258X
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author Zhang, Jing
Li, Ping
Liu, Zhi-Hong
Ng, Seik Weng
author_facet Zhang, Jing
Li, Ping
Liu, Zhi-Hong
Ng, Seik Weng
author_sort Zhang, Jing
collection PubMed
description The title manganese(II) substituted gallophosphate, K(0.5)Rb(0.5)[Ga(2)Mn(PO(4))(3)(H(2)O)(2)], features a three-dimensional network built of PO(4) tetra­hedra, GaO(5) trigonal bipyramids and MnO(6) octa­hedra. The Rb(I) and K(I) ions, which are disordered with respect to each other in a 1:1 ratio, occupy sites within the channels of the framework. The Rb(I)/K(I) and Mn(II) atoms occupy positions of 2 symmetry, as does one of the two P atoms. The Rb(I)/K(I) site is surrounded by six O atoms [2.996 (2)–3.178 (4) Å] in an irregularly-shaped coordination environment. O—H⋯O hydrogen bonds between the water molecules and phosphate O atoms consolidate the crystal packing.
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spelling pubmed-30891902011-07-13 Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate Zhang, Jing Li, Ping Liu, Zhi-Hong Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title manganese(II) substituted gallophosphate, K(0.5)Rb(0.5)[Ga(2)Mn(PO(4))(3)(H(2)O)(2)], features a three-dimensional network built of PO(4) tetra­hedra, GaO(5) trigonal bipyramids and MnO(6) octa­hedra. The Rb(I) and K(I) ions, which are disordered with respect to each other in a 1:1 ratio, occupy sites within the channels of the framework. The Rb(I)/K(I) and Mn(II) atoms occupy positions of 2 symmetry, as does one of the two P atoms. The Rb(I)/K(I) site is surrounded by six O atoms [2.996 (2)–3.178 (4) Å] in an irregularly-shaped coordination environment. O—H⋯O hydrogen bonds between the water molecules and phosphate O atoms consolidate the crystal packing. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089190/ /pubmed/21754256 http://dx.doi.org/10.1107/S160053681101258X Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhang, Jing
Li, Ping
Liu, Zhi-Hong
Ng, Seik Weng
Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate
title Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate
title_full Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate
title_fullStr Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate
title_full_unstemmed Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate
title_short Hemipotassium hemirubidium digallium(III) manganese(II) tris(phos­phate) dihydrate
title_sort hemipotassium hemirubidium digallium(iii) manganese(ii) tris(phos­phate) dihydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089190/
https://www.ncbi.nlm.nih.gov/pubmed/21754256
http://dx.doi.org/10.1107/S160053681101258X
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AT liping hemipotassiumhemirubidiumdigalliumiiimanganeseiitrisphosphatedihydrate
AT liuzhihong hemipotassiumhemirubidiumdigalliumiiimanganeseiitrisphosphatedihydrate
AT ngseikweng hemipotassiumhemirubidiumdigalliumiiimanganeseiitrisphosphatedihydrate

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