Cargando…

N,N′-Bis(2-chloro­phen­yl)succinamide

There is one half-mol­ecule in the asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(2), with a center of symmetry at the mid-point of the central C—C bond. The N—H and C=O bonds in the C—NH—C(O)—C fragment are anti to each other and the amide O atom is anti to the H atoms attached to the...

Descripción completa

Detalles Bibliográficos
Autores principales: Saraswathi, B. S., Foro, Sabine, Gowda, B. Thimme
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089196/
https://www.ncbi.nlm.nih.gov/pubmed/21754448
http://dx.doi.org/10.1107/S1600536811013407
_version_ 1782203000382554112
author Saraswathi, B. S.
Foro, Sabine
Gowda, B. Thimme
author_facet Saraswathi, B. S.
Foro, Sabine
Gowda, B. Thimme
author_sort Saraswathi, B. S.
collection PubMed
description There is one half-mol­ecule in the asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(2), with a center of symmetry at the mid-point of the central C—C bond. The N—H and C=O bonds in the C—NH—C(O)—C fragment are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. However, the conformation of the N—H bond in the amide fragments is syn to the ortho-chloro groups in the adjacent benzene rings. The dihedral angle between the benzene ring and the NH—C(O)—CH(2) fragment is 47.0 (2)°. In the crystal, a series of N—H⋯O inter­molecular hydrogen bonds link the mol­ecules into chains along the b axis.
format Text
id pubmed-3089196
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30891962011-07-13 N,N′-Bis(2-chloro­phen­yl)succinamide Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers There is one half-mol­ecule in the asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(2), with a center of symmetry at the mid-point of the central C—C bond. The N—H and C=O bonds in the C—NH—C(O)—C fragment are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. However, the conformation of the N—H bond in the amide fragments is syn to the ortho-chloro groups in the adjacent benzene rings. The dihedral angle between the benzene ring and the NH—C(O)—CH(2) fragment is 47.0 (2)°. In the crystal, a series of N—H⋯O inter­molecular hydrogen bonds link the mol­ecules into chains along the b axis. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089196/ /pubmed/21754448 http://dx.doi.org/10.1107/S1600536811013407 Text en © Saraswathi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saraswathi, B. S.
Foro, Sabine
Gowda, B. Thimme
N,N′-Bis(2-chloro­phen­yl)succinamide
title N,N′-Bis(2-chloro­phen­yl)succinamide
title_full N,N′-Bis(2-chloro­phen­yl)succinamide
title_fullStr N,N′-Bis(2-chloro­phen­yl)succinamide
title_full_unstemmed N,N′-Bis(2-chloro­phen­yl)succinamide
title_short N,N′-Bis(2-chloro­phen­yl)succinamide
title_sort n,n′-bis(2-chloro­phen­yl)succinamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089196/
https://www.ncbi.nlm.nih.gov/pubmed/21754448
http://dx.doi.org/10.1107/S1600536811013407
work_keys_str_mv AT saraswathibs nnbis2chlorophenylsuccinamide
AT forosabine nnbis2chlorophenylsuccinamide
AT gowdabthimme nnbis2chlorophenylsuccinamide