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N,N′-Bis(2-chlorophenyl)succinamide
There is one half-molecule in the asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(2), with a center of symmetry at the mid-point of the central C—C bond. The N—H and C=O bonds in the C—NH—C(O)—C fragment are anti to each other and the amide O atom is anti to the H atoms attached to the...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089196/ https://www.ncbi.nlm.nih.gov/pubmed/21754448 http://dx.doi.org/10.1107/S1600536811013407 |
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author | Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme |
author_facet | Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme |
author_sort | Saraswathi, B. S. |
collection | PubMed |
description | There is one half-molecule in the asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(2), with a center of symmetry at the mid-point of the central C—C bond. The N—H and C=O bonds in the C—NH—C(O)—C fragment are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. However, the conformation of the N—H bond in the amide fragments is syn to the ortho-chloro groups in the adjacent benzene rings. The dihedral angle between the benzene ring and the NH—C(O)—CH(2) fragment is 47.0 (2)°. In the crystal, a series of N—H⋯O intermolecular hydrogen bonds link the molecules into chains along the b axis. |
format | Text |
id | pubmed-3089196 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891962011-07-13 N,N′-Bis(2-chlorophenyl)succinamide Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers There is one half-molecule in the asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(2), with a center of symmetry at the mid-point of the central C—C bond. The N—H and C=O bonds in the C—NH—C(O)—C fragment are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. However, the conformation of the N—H bond in the amide fragments is syn to the ortho-chloro groups in the adjacent benzene rings. The dihedral angle between the benzene ring and the NH—C(O)—CH(2) fragment is 47.0 (2)°. In the crystal, a series of N—H⋯O intermolecular hydrogen bonds link the molecules into chains along the b axis. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089196/ /pubmed/21754448 http://dx.doi.org/10.1107/S1600536811013407 Text en © Saraswathi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme N,N′-Bis(2-chlorophenyl)succinamide |
title |
N,N′-Bis(2-chlorophenyl)succinamide |
title_full |
N,N′-Bis(2-chlorophenyl)succinamide |
title_fullStr |
N,N′-Bis(2-chlorophenyl)succinamide |
title_full_unstemmed |
N,N′-Bis(2-chlorophenyl)succinamide |
title_short |
N,N′-Bis(2-chlorophenyl)succinamide |
title_sort | n,n′-bis(2-chlorophenyl)succinamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089196/ https://www.ncbi.nlm.nih.gov/pubmed/21754448 http://dx.doi.org/10.1107/S1600536811013407 |
work_keys_str_mv | AT saraswathibs nnbis2chlorophenylsuccinamide AT forosabine nnbis2chlorophenylsuccinamide AT gowdabthimme nnbis2chlorophenylsuccinamide |