A novel lithium copper iron phosphate with idealized formula Li(5)Cu(2) (2+)Fe(3+)(PO(4))(4): crystal structure and distribution of defects

Gray–green single crystals were obtained under high-pressure, high-temperature hydro­thermal conditions. A refinement of atom occupancies gave the composition Li(3.68)Cu(2+)Fe(3+)(Cu(0.55)Li(0.45))(2)Fe(2+) (0.15)(PO(4))(4). The structure is built from triplets of edge-sharing (Cu,Li)O(5)–FeO(6)–(Cu...

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Detalles Bibliográficos
Autores principales: Upreti, Shailesh, Yakubovich, Olga V., Chernova, Natasha A., Whittingham, M. Stanley
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089199/
https://www.ncbi.nlm.nih.gov/pubmed/21754255
http://dx.doi.org/10.1107/S1600536811011755

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