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A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide
The title compound, bis[μ-(E)-2-({2-[4-(dimethylamino)benzoyl]hydrazinylidene}methyl)phenolato]bis[formatozinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethylamino-N′-(2-hydr...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089200/ https://www.ncbi.nlm.nih.gov/pubmed/21754335 http://dx.doi.org/10.1107/S1600536811014462 |
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author | Ma, Jie Fan, Wei-Zhen Lin, Li-Rong |
author_facet | Ma, Jie Fan, Wei-Zhen Lin, Li-Rong |
author_sort | Ma, Jie |
collection | PubMed |
description | The title compound, bis[μ-(E)-2-({2-[4-(dimethylamino)benzoyl]hydrazinylidene}methyl)phenolato]bis[formatozinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide (L), and two formate ions. Each Zn(II) atom chelates with the hydroxy O atom of salicylaldehyde, the imine N atom, the carbonyl O atom, the formate carboxylate O atom and the hydroxy O atom of the salicylaldehyde moiety in a symmetry-related unit. The five-coordinate Zn(II) atoms form a dimeric centrosymmetric unit with a central parallelepiped Zn(2)O(2) core and parallel faces derived from the Schiff base ligands. The crystal packing is stabilized by intermolecular N—H⋯O hydrogen bonds between the amide N atom and the formate carboxylate O atom. |
format | Text |
id | pubmed-3089200 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892002011-07-13 A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide Ma, Jie Fan, Wei-Zhen Lin, Li-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, bis[μ-(E)-2-({2-[4-(dimethylamino)benzoyl]hydrazinylidene}methyl)phenolato]bis[formatozinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide (L), and two formate ions. Each Zn(II) atom chelates with the hydroxy O atom of salicylaldehyde, the imine N atom, the carbonyl O atom, the formate carboxylate O atom and the hydroxy O atom of the salicylaldehyde moiety in a symmetry-related unit. The five-coordinate Zn(II) atoms form a dimeric centrosymmetric unit with a central parallelepiped Zn(2)O(2) core and parallel faces derived from the Schiff base ligands. The crystal packing is stabilized by intermolecular N—H⋯O hydrogen bonds between the amide N atom and the formate carboxylate O atom. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089200/ /pubmed/21754335 http://dx.doi.org/10.1107/S1600536811014462 Text en © Ma et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Jie Fan, Wei-Zhen Lin, Li-Rong A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide |
title | A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide |
title_full | A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide |
title_fullStr | A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide |
title_full_unstemmed | A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide |
title_short | A dinuclear zinc complex with (E)-4-dimethylamino-N′-(2-hydroxybenzylidene)benzohydrazide |
title_sort | dinuclear zinc complex with (e)-4-dimethylamino-n′-(2-hydroxybenzylidene)benzohydrazide |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089200/ https://www.ncbi.nlm.nih.gov/pubmed/21754335 http://dx.doi.org/10.1107/S1600536811014462 |
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