Cargando…

A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide

The title compound, bis­[μ-(E)-2-({2-[4-(dimethyl­amino)­benzo­yl]hydrazinyl­idene}meth­yl)phenolato]bis­[formato­zinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethyl­amino-N′-(2-hy­dr...

Descripción completa

Detalles Bibliográficos
Autores principales: Ma, Jie, Fan, Wei-Zhen, Lin, Li-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089200/
https://www.ncbi.nlm.nih.gov/pubmed/21754335
http://dx.doi.org/10.1107/S1600536811014462
_version_ 1782203001312641024
author Ma, Jie
Fan, Wei-Zhen
Lin, Li-Rong
author_facet Ma, Jie
Fan, Wei-Zhen
Lin, Li-Rong
author_sort Ma, Jie
collection PubMed
description The title compound, bis­[μ-(E)-2-({2-[4-(dimethyl­amino)­benzo­yl]hydrazinyl­idene}meth­yl)phenolato]bis­[formato­zinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide (L), and two formate ions. Each Zn(II) atom chelates with the hy­droxy O atom of salicyl­aldehyde, the imine N atom, the carbonyl O atom, the formate carboxyl­ate O atom and the hy­droxy O atom of the salicyl­aldehyde moiety in a symmetry-related unit. The five-coordinate Zn(II) atoms form a dimeric centrosymmetric unit with a central parallelepiped Zn(2)O(2) core and parallel faces derived from the Schiff base ligands. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds between the amide N atom and the formate carboxyl­ate O atom.
format Text
id pubmed-3089200
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30892002011-07-13 A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide Ma, Jie Fan, Wei-Zhen Lin, Li-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, bis­[μ-(E)-2-({2-[4-(dimethyl­amino)­benzo­yl]hydrazinyl­idene}meth­yl)phenolato]bis­[formato­zinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide (L), and two formate ions. Each Zn(II) atom chelates with the hy­droxy O atom of salicyl­aldehyde, the imine N atom, the carbonyl O atom, the formate carboxyl­ate O atom and the hy­droxy O atom of the salicyl­aldehyde moiety in a symmetry-related unit. The five-coordinate Zn(II) atoms form a dimeric centrosymmetric unit with a central parallelepiped Zn(2)O(2) core and parallel faces derived from the Schiff base ligands. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds between the amide N atom and the formate carboxyl­ate O atom. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089200/ /pubmed/21754335 http://dx.doi.org/10.1107/S1600536811014462 Text en © Ma et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Jie
Fan, Wei-Zhen
Lin, Li-Rong
A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide
title A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide
title_full A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide
title_fullStr A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide
title_full_unstemmed A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide
title_short A dinuclear zinc complex with (E)-4-dimethyl­amino-N′-(2-hy­droxy­benzyl­idene)benzohydrazide
title_sort dinuclear zinc complex with (e)-4-dimethyl­amino-n′-(2-hy­droxy­benzyl­idene)benzohydrazide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089200/
https://www.ncbi.nlm.nih.gov/pubmed/21754335
http://dx.doi.org/10.1107/S1600536811014462
work_keys_str_mv AT majie adinuclearzinccomplexwithe4dimethylaminon2hydroxybenzylidenebenzohydrazide
AT fanweizhen adinuclearzinccomplexwithe4dimethylaminon2hydroxybenzylidenebenzohydrazide
AT linlirong adinuclearzinccomplexwithe4dimethylaminon2hydroxybenzylidenebenzohydrazide
AT majie dinuclearzinccomplexwithe4dimethylaminon2hydroxybenzylidenebenzohydrazide
AT fanweizhen dinuclearzinccomplexwithe4dimethylaminon2hydroxybenzylidenebenzohydrazide
AT linlirong dinuclearzinccomplexwithe4dimethylaminon2hydroxybenzylidenebenzohydrazide