(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine

The mol­ecule of the title compound, C(12)H(10)N(4)O(4)S, is slightly twisted, with a dihedral angle of 8.23 (9)° between the benzene and thio­phene rings. One nitro group is co-planar [O—N—C—C torsion angles = −0.5 (3) and −1.9 (3)°] whereas the other is slightly twisted with respect to the benzene...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Jansrisewangwong, Patcharaporn, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089201/
https://www.ncbi.nlm.nih.gov/pubmed/21754363
http://dx.doi.org/10.1107/S1600536811011135
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author Fun, Hoong-Kun
Jansrisewangwong, Patcharaporn
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Jansrisewangwong, Patcharaporn
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title compound, C(12)H(10)N(4)O(4)S, is slightly twisted, with a dihedral angle of 8.23 (9)° between the benzene and thio­phene rings. One nitro group is co-planar [O—N—C—C torsion angles = −0.5 (3) and −1.9 (3)°] whereas the other is slightly twisted with respect to the benzene ring [O—N—C—C torsion angles = −5.1 (3) and −5.7 (3)°]. In the crystal, the mol­ecules are linked by weak C—H⋯O inter­actions into screw chains along the b axis. The mol­ecular conformation is consolidated by an intra­molecular N—H⋯O hydrogen bond.
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spelling pubmed-30892012011-07-13 (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine Fun, Hoong-Kun Jansrisewangwong, Patcharaporn Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(12)H(10)N(4)O(4)S, is slightly twisted, with a dihedral angle of 8.23 (9)° between the benzene and thio­phene rings. One nitro group is co-planar [O—N—C—C torsion angles = −0.5 (3) and −1.9 (3)°] whereas the other is slightly twisted with respect to the benzene ring [O—N—C—C torsion angles = −5.1 (3) and −5.7 (3)°]. In the crystal, the mol­ecules are linked by weak C—H⋯O inter­actions into screw chains along the b axis. The mol­ecular conformation is consolidated by an intra­molecular N—H⋯O hydrogen bond. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089201/ /pubmed/21754363 http://dx.doi.org/10.1107/S1600536811011135 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jansrisewangwong, Patcharaporn
Chantrapromma, Suchada
(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
title (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
title_full (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
title_fullStr (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
title_full_unstemmed (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
title_short (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
title_sort (e)-1-(2,4-dinitro­phen­yl)-2-[1-(thio­phen-2-yl)ethyl­idene]hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089201/
https://www.ncbi.nlm.nih.gov/pubmed/21754363
http://dx.doi.org/10.1107/S1600536811011135
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AT jansrisewangwongpatcharaporn e124dinitrophenyl21thiophen2ylethylidenehydrazine
AT chantraprommasuchada e124dinitrophenyl21thiophen2ylethylidenehydrazine

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