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Poly[[μ-aqua-bis(μ-4,4′-bipyridine-κ(2) N:N′)bis(μ-3-hydroxyadamantane-1-carboxylato-κ(2) O:O′)bis(3-hydroxyadamantane-1-carboxylato-κO)dicobalt(II)] heptahydrate]
The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hydroxyadamantane-1-carboxylate anions (L), one water molecule, two bridging 4,4′-bipyridine (4,4′-bpy) ligands and seven uncoordinated water molecules. Both...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089202/ https://www.ncbi.nlm.nih.gov/pubmed/21754291 http://dx.doi.org/10.1107/S1600536811012475 |
Sumario: | The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hydroxyadamantane-1-carboxylate anions (L), one water molecule, two bridging 4,4′-bipyridine (4,4′-bpy) ligands and seven uncoordinated water molecules. Both of the Co(II) ions are coordinated in a distorted octahedral geometry. Four L ligands bind to each pair of Co(II) atoms in a plane, two of which bridge the two Co(II) atoms as bidentate groups while the other two coordinate to a single Co(II) atom in a monodentate mode. Two half-molecules of 4,4′-bipyridine coordinate the Co(II) atoms from the upside and underside. The packing features extensice O—H⋯O hydrogen bonding. |
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