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Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]

The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy­droxy­adamantane-1-carboxyl­ate anions (L), one water mol­ecule, two bridging 4,4′-bipyridine (4,4′-bpy) ligands and seven uncoordinated water mol­ecules. Both...

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Detalles Bibliográficos
Autores principales: Shen, Jin-Bei, Wu, Xiao-Yong, Chen, Xiao-Ju, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089202/
https://www.ncbi.nlm.nih.gov/pubmed/21754291
http://dx.doi.org/10.1107/S1600536811012475
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author Shen, Jin-Bei
Wu, Xiao-Yong
Chen, Xiao-Ju
Zhao, Guo-Liang
author_facet Shen, Jin-Bei
Wu, Xiao-Yong
Chen, Xiao-Ju
Zhao, Guo-Liang
author_sort Shen, Jin-Bei
collection PubMed
description The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy­droxy­adamantane-1-carboxyl­ate anions (L), one water mol­ecule, two bridging 4,4′-bipyridine (4,4′-bpy) ligands and seven uncoordinated water mol­ecules. Both of the Co(II) ions are coordinated in a distorted octa­hedral geometry. Four L ligands bind to each pair of Co(II) atoms in a plane, two of which bridge the two Co(II) atoms as bidentate groups while the other two coordinate to a single Co(II) atom in a monodentate mode. Two half-mol­ecules of 4,4′-bipyridine coordinate the Co(II) atoms from the upside and underside. The packing features extensice O—H⋯O hydrogen bonding.
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spelling pubmed-30892022011-07-13 Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate] Shen, Jin-Bei Wu, Xiao-Yong Chen, Xiao-Ju Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy­droxy­adamantane-1-carboxyl­ate anions (L), one water mol­ecule, two bridging 4,4′-bipyridine (4,4′-bpy) ligands and seven uncoordinated water mol­ecules. Both of the Co(II) ions are coordinated in a distorted octa­hedral geometry. Four L ligands bind to each pair of Co(II) atoms in a plane, two of which bridge the two Co(II) atoms as bidentate groups while the other two coordinate to a single Co(II) atom in a monodentate mode. Two half-mol­ecules of 4,4′-bipyridine coordinate the Co(II) atoms from the upside and underside. The packing features extensice O—H⋯O hydrogen bonding. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089202/ /pubmed/21754291 http://dx.doi.org/10.1107/S1600536811012475 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Jin-Bei
Wu, Xiao-Yong
Chen, Xiao-Ju
Zhao, Guo-Liang
Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]
title Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]
title_full Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]
title_fullStr Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]
title_full_unstemmed Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]
title_short Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]
title_sort poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ(2) n:n′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ(2) o:o′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κo)dicobalt(ii)] hepta­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089202/
https://www.ncbi.nlm.nih.gov/pubmed/21754291
http://dx.doi.org/10.1107/S1600536811012475
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