The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}

The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butyl­amino)-2-(tert-butyl­imino)-1,3,2λ(5),4-diaza­diphosphetidin-2-yl]-1-(4-meth­oxy­phen­yl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ(5)-dioxaphosphinan-2-one, C(31)H(57)N(4)O(4)P(3), was synthesized from the Phospha–Michael addition reaction of cyclo...

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Detalles Bibliográficos
Autores principales: Gangadhararao, G., Venu, Srinivas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089203/
https://www.ncbi.nlm.nih.gov/pubmed/21754511
http://dx.doi.org/10.1107/S1600536811014127
Descripción
Sumario:The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butyl­amino)-2-(tert-butyl­imino)-1,3,2λ(5),4-diaza­diphosphetidin-2-yl]-1-(4-meth­oxy­phen­yl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ(5)-dioxaphosphinan-2-one, C(31)H(57)N(4)O(4)P(3), was synthesized from the Phospha–Michael addition reaction of cyclo­diphos­pha­zane [(t-BuNH)P(μ-Nt-Bu)](2) and allenyl­phospho­nate [(OCH(2)C(CH(3))(2)CH(2)O)P(O)C(p-CH(3)O—C(6)H(4))=C=CH(2)]. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules. The structure exhibits pseudosymmetry but attempts to solve it in a higher (monoclinic) space group were unsuccessful.

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