The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}

The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butyl­amino)-2-(tert-butyl­imino)-1,3,2λ(5),4-diaza­diphosphetidin-2-yl]-1-(4-meth­oxy­phen­yl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ(5)-dioxaphosphinan-2-one, C(31)H(57)N(4)O(4)P(3), was synthesized from the Phospha–Michael addition reaction of cyclo...

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Detalles Bibliográficos
Autores principales: Gangadhararao, G., Venu, Srinivas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089203/
https://www.ncbi.nlm.nih.gov/pubmed/21754511
http://dx.doi.org/10.1107/S1600536811014127
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author Gangadhararao, G.
Venu, Srinivas
author_facet Gangadhararao, G.
Venu, Srinivas
author_sort Gangadhararao, G.
collection PubMed
description The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butyl­amino)-2-(tert-butyl­imino)-1,3,2λ(5),4-diaza­diphosphetidin-2-yl]-1-(4-meth­oxy­phen­yl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ(5)-dioxaphosphinan-2-one, C(31)H(57)N(4)O(4)P(3), was synthesized from the Phospha–Michael addition reaction of cyclo­diphos­pha­zane [(t-BuNH)P(μ-Nt-Bu)](2) and allenyl­phospho­nate [(OCH(2)C(CH(3))(2)CH(2)O)P(O)C(p-CH(3)O—C(6)H(4))=C=CH(2)]. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules. The structure exhibits pseudosymmetry but attempts to solve it in a higher (monoclinic) space group were unsuccessful.
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spelling pubmed-30892032011-07-13 The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]} Gangadhararao, G. Venu, Srinivas Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butyl­amino)-2-(tert-butyl­imino)-1,3,2λ(5),4-diaza­diphosphetidin-2-yl]-1-(4-meth­oxy­phen­yl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ(5)-dioxaphosphinan-2-one, C(31)H(57)N(4)O(4)P(3), was synthesized from the Phospha–Michael addition reaction of cyclo­diphos­pha­zane [(t-BuNH)P(μ-Nt-Bu)](2) and allenyl­phospho­nate [(OCH(2)C(CH(3))(2)CH(2)O)P(O)C(p-CH(3)O—C(6)H(4))=C=CH(2)]. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules. The structure exhibits pseudosymmetry but attempts to solve it in a higher (monoclinic) space group were unsuccessful. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089203/ /pubmed/21754511 http://dx.doi.org/10.1107/S1600536811014127 Text en © Gangadhararao and Venu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gangadhararao, G.
Venu, Srinivas
The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
title The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
title_full The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
title_fullStr The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
title_full_unstemmed The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
title_short The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
title_sort phospha–michael addition product {(t-bunh)p(μ-n-t-bu)(2)p(=n-t-bu)—c(=ch(2))ch(p-ch(3)o—c(6)h(4))-p(o)[(och(2)c(ch(3))(2)ch(2)o)]}
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089203/
https://www.ncbi.nlm.nih.gov/pubmed/21754511
http://dx.doi.org/10.1107/S1600536811014127
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