(5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)

In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa­hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3)...

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Detalles Bibliográficos
Autores principales: Lundvall, Fredrik, Wragg, David Stephen, Tilset, Mats
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089208/
https://www.ncbi.nlm.nih.gov/pubmed/21754331
http://dx.doi.org/10.1107/S1600536811014085
Descripción
Sumario:In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa­hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand.

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