(5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)

In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa­hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3)...

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Detalles Bibliográficos
Autores principales: Lundvall, Fredrik, Wragg, David Stephen, Tilset, Mats
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089208/
https://www.ncbi.nlm.nih.gov/pubmed/21754331
http://dx.doi.org/10.1107/S1600536811014085
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author Lundvall, Fredrik
Wragg, David Stephen
Tilset, Mats
author_facet Lundvall, Fredrik
Wragg, David Stephen
Tilset, Mats
author_sort Lundvall, Fredrik
collection PubMed
description In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa­hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand.
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spelling pubmed-30892082011-07-13 (5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV) Lundvall, Fredrik Wragg, David Stephen Tilset, Mats Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa­hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089208/ /pubmed/21754331 http://dx.doi.org/10.1107/S1600536811014085 Text en © Lundvall et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lundvall, Fredrik
Wragg, David Stephen
Tilset, Mats
(5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)
title (5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)
title_full (5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)
title_fullStr (5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)
title_full_unstemmed (5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)
title_short (5,5′-Dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(IV)
title_sort (5,5′-dimethyl-2,2′-bipyridine)­iodido­trimethyl­platinum(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089208/
https://www.ncbi.nlm.nih.gov/pubmed/21754331
http://dx.doi.org/10.1107/S1600536811014085
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AT wraggdavidstephen 55dimethyl22bipyridineiodidotrimethylplatinumiv
AT tilsetmats 55dimethyl22bipyridineiodidotrimethylplatinumiv

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