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Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate
The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyridyl)(2-pyridylamino)methanolate ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coor...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089209/ https://www.ncbi.nlm.nih.gov/pubmed/21754334 http://dx.doi.org/10.1107/S1600536811014371 |
Sumario: | The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyridyl)(2-pyridylamino)methanolate ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methanolate O atoms occupy the axial positions. The coordination geometry is thus octahedral. In the title compound, the cations are linked by nitrate anions via N—H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by intermolecular edge-to-face aromatic π–π interactions with a center-of-inversion at a distance of ca 4.634 Å. |
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