Cargando…

Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate

The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyrid­yl)(2-pyridyl­amino)­methano­late ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coor...

Descripción completa

Detalles Bibliográficos
Autores principales: Ding, Shuai, Xia, Congjun, Ji, Yufei, Liu, Zhiliang, Ding, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089209/
https://www.ncbi.nlm.nih.gov/pubmed/21754334
http://dx.doi.org/10.1107/S1600536811014371
Descripción
Sumario:The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyrid­yl)(2-pyridyl­amino)­methano­late ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methano­late O atoms occupy the axial positions. The coordination geometry is thus octa­hedral. In the title compound, the cations are linked by nitrate anions via N—H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by inter­molecular edge-to-face aromatic π–π inter­actions with a center-of-inversion at a distance of ca 4.634 Å.