Cargando…
Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate
The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyridyl)(2-pyridylamino)methanolate ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coor...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089209/ https://www.ncbi.nlm.nih.gov/pubmed/21754334 http://dx.doi.org/10.1107/S1600536811014371 |
_version_ | 1782203003419230208 |
---|---|
author | Ding, Shuai Xia, Congjun Ji, Yufei Liu, Zhiliang Ding, Yong |
author_facet | Ding, Shuai Xia, Congjun Ji, Yufei Liu, Zhiliang Ding, Yong |
author_sort | Ding, Shuai |
collection | PubMed |
description | The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyridyl)(2-pyridylamino)methanolate ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methanolate O atoms occupy the axial positions. The coordination geometry is thus octahedral. In the title compound, the cations are linked by nitrate anions via N—H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by intermolecular edge-to-face aromatic π–π interactions with a center-of-inversion at a distance of ca 4.634 Å. |
format | Text |
id | pubmed-3089209 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892092011-07-13 Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate Ding, Shuai Xia, Congjun Ji, Yufei Liu, Zhiliang Ding, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyridyl)(2-pyridylamino)methanolate ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methanolate O atoms occupy the axial positions. The coordination geometry is thus octahedral. In the title compound, the cations are linked by nitrate anions via N—H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by intermolecular edge-to-face aromatic π–π interactions with a center-of-inversion at a distance of ca 4.634 Å. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089209/ /pubmed/21754334 http://dx.doi.org/10.1107/S1600536811014371 Text en © Ding et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ding, Shuai Xia, Congjun Ji, Yufei Liu, Zhiliang Ding, Yong Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate |
title | Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate |
title_full | Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate |
title_fullStr | Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate |
title_full_unstemmed | Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate |
title_short | Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate |
title_sort | bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(iii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089209/ https://www.ncbi.nlm.nih.gov/pubmed/21754334 http://dx.doi.org/10.1107/S1600536811014371 |
work_keys_str_mv | AT dingshuai bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate AT xiacongjun bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate AT jiyufei bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate AT liuzhiliang bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate AT dingyong bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate |