Cargando…

Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate

The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyrid­yl)(2-pyridyl­amino)­methano­late ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coor...

Descripción completa

Detalles Bibliográficos
Autores principales: Ding, Shuai, Xia, Congjun, Ji, Yufei, Liu, Zhiliang, Ding, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089209/
https://www.ncbi.nlm.nih.gov/pubmed/21754334
http://dx.doi.org/10.1107/S1600536811014371
_version_ 1782203003419230208
author Ding, Shuai
Xia, Congjun
Ji, Yufei
Liu, Zhiliang
Ding, Yong
author_facet Ding, Shuai
Xia, Congjun
Ji, Yufei
Liu, Zhiliang
Ding, Yong
author_sort Ding, Shuai
collection PubMed
description The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyrid­yl)(2-pyridyl­amino)­methano­late ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methano­late O atoms occupy the axial positions. The coordination geometry is thus octa­hedral. In the title compound, the cations are linked by nitrate anions via N—H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by inter­molecular edge-to-face aromatic π–π inter­actions with a center-of-inversion at a distance of ca 4.634 Å.
format Text
id pubmed-3089209
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30892092011-07-13 Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate Ding, Shuai Xia, Congjun Ji, Yufei Liu, Zhiliang Ding, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyrid­yl)(2-pyridyl­amino)­methano­late ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methano­late O atoms occupy the axial positions. The coordination geometry is thus octa­hedral. In the title compound, the cations are linked by nitrate anions via N—H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by inter­molecular edge-to-face aromatic π–π inter­actions with a center-of-inversion at a distance of ca 4.634 Å. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089209/ /pubmed/21754334 http://dx.doi.org/10.1107/S1600536811014371 Text en © Ding et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, Shuai
Xia, Congjun
Ji, Yufei
Liu, Zhiliang
Ding, Yong
Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate
title Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate
title_full Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate
title_fullStr Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate
title_full_unstemmed Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate
title_short Bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(III) nitrate
title_sort bis[(2-pyrid­yl)(2-pyridyl­amino)­methano­lato]manganese(iii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089209/
https://www.ncbi.nlm.nih.gov/pubmed/21754334
http://dx.doi.org/10.1107/S1600536811014371
work_keys_str_mv AT dingshuai bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate
AT xiacongjun bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate
AT jiyufei bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate
AT liuzhiliang bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate
AT dingyong bis2pyridyl2pyridylaminomethanolatomanganeseiiinitrate