Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate

Reaction of 5-sulfosalicylic acid with hydrazine hydrate at pH = 1 results in the formation of the title hydrated salt, 0.5N(2)H(6) (2+)·C(7)H(5)O(6)S(−)·2H(2)O. The hydrazinium dications lie on centres of inversion. They are located between 3-carb­oxy-4-hy­droxy­benzene­sulfonate anions, forming in...

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Detalles Bibliográficos
Autores principales: Selvaraju, Devipriya, Venkatesh, Ranjithkumar, Sundararajan, Vairam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089212/
https://www.ncbi.nlm.nih.gov/pubmed/21754532
http://dx.doi.org/10.1107/S1600536811014231
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author Selvaraju, Devipriya
Venkatesh, Ranjithkumar
Sundararajan, Vairam
author_facet Selvaraju, Devipriya
Venkatesh, Ranjithkumar
Sundararajan, Vairam
author_sort Selvaraju, Devipriya
collection PubMed
description Reaction of 5-sulfosalicylic acid with hydrazine hydrate at pH = 1 results in the formation of the title hydrated salt, 0.5N(2)H(6) (2+)·C(7)H(5)O(6)S(−)·2H(2)O. The hydrazinium dications lie on centres of inversion. They are located between 3-carb­oxy-4-hy­droxy­benzene­sulfonate anions, forming inter­molecular N—H⋯O hydrogen bonds with sulfonate ions and water mol­ecules of crystallisation. Further intra- and inter­molecular O—H⋯O hydrogen bonds are observed in the crystal structure.
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spelling pubmed-30892122011-07-13 Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate Selvaraju, Devipriya Venkatesh, Ranjithkumar Sundararajan, Vairam Acta Crystallogr Sect E Struct Rep Online Organic Papers Reaction of 5-sulfosalicylic acid with hydrazine hydrate at pH = 1 results in the formation of the title hydrated salt, 0.5N(2)H(6) (2+)·C(7)H(5)O(6)S(−)·2H(2)O. The hydrazinium dications lie on centres of inversion. They are located between 3-carb­oxy-4-hy­droxy­benzene­sulfonate anions, forming inter­molecular N—H⋯O hydrogen bonds with sulfonate ions and water mol­ecules of crystallisation. Further intra- and inter­molecular O—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089212/ /pubmed/21754532 http://dx.doi.org/10.1107/S1600536811014231 Text en © Selvaraju et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvaraju, Devipriya
Venkatesh, Ranjithkumar
Sundararajan, Vairam
Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
title Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
title_full Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
title_fullStr Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
title_full_unstemmed Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
title_short Hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
title_sort hydrazine-1,2-diium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) tetra­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089212/
https://www.ncbi.nlm.nih.gov/pubmed/21754532
http://dx.doi.org/10.1107/S1600536811014231
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AT venkateshranjithkumar hydrazine12diiumbis3carboxy4hydroxybenzenesulfonatetetrahydrate
AT sundararajanvairam hydrazine12diiumbis3carboxy4hydroxybenzenesulfonatetetrahydrate

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