(8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate

In the title compound, C(26)H(28)Cl(N)O(4)·H(2)O, the dihedral angle betwene the two aromatic rings is 69.73 (6)°. The N-containing ring exhibits a chair conformation, while the other non-aromatic rings are in approximate envelope conformations. In the crystal, the water mol­ecule forms O—H⋯O and O—...

Descripción completa

Detalles Bibliográficos
Autores principales: Zheng, Xing-Liang, Chen, Shu-Jun, Jiang, Ning-Fei, Zhan, Sue-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089213/
https://www.ncbi.nlm.nih.gov/pubmed/21754492
http://dx.doi.org/10.1107/S1600536811013973
_version_ 1782203004360851456
author Zheng, Xing-Liang
Chen, Shu-Jun
Jiang, Ning-Fei
Zhan, Sue-Hui
author_facet Zheng, Xing-Liang
Chen, Shu-Jun
Jiang, Ning-Fei
Zhan, Sue-Hui
author_sort Zheng, Xing-Liang
collection PubMed
description In the title compound, C(26)H(28)Cl(N)O(4)·H(2)O, the dihedral angle betwene the two aromatic rings is 69.73 (6)°. The N-containing ring exhibits a chair conformation, while the other non-aromatic rings are in approximate envelope conformations. In the crystal, the water mol­ecule forms O—H⋯O and O—H⋯N hydrogen bonds and a C—H⋯O link also occurs.
format Text
id pubmed-3089213
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30892132011-07-13 (8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate Zheng, Xing-Liang Chen, Shu-Jun Jiang, Ning-Fei Zhan, Sue-Hui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(28)Cl(N)O(4)·H(2)O, the dihedral angle betwene the two aromatic rings is 69.73 (6)°. The N-containing ring exhibits a chair conformation, while the other non-aromatic rings are in approximate envelope conformations. In the crystal, the water mol­ecule forms O—H⋯O and O—H⋯N hydrogen bonds and a C—H⋯O link also occurs. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089213/ /pubmed/21754492 http://dx.doi.org/10.1107/S1600536811013973 Text en © Zheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zheng, Xing-Liang
Chen, Shu-Jun
Jiang, Ning-Fei
Zhan, Sue-Hui
(8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title (8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_full (8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_fullStr (8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_full_unstemmed (8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_short (8S,9S,10R)-4-(4-Chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_sort (8s,9s,10r)-4-(4-chloro­benz­yloxy)-7,8-didehydro-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089213/
https://www.ncbi.nlm.nih.gov/pubmed/21754492
http://dx.doi.org/10.1107/S1600536811013973
work_keys_str_mv AT zhengxingliang 8s9s10r44chlorobenzyloxy78didehydro37dimethoxy17methylmorphinan6onemonohydrate
AT chenshujun 8s9s10r44chlorobenzyloxy78didehydro37dimethoxy17methylmorphinan6onemonohydrate
AT jiangningfei 8s9s10r44chlorobenzyloxy78didehydro37dimethoxy17methylmorphinan6onemonohydrate
AT zhansuehui 8s9s10r44chlorobenzyloxy78didehydro37dimethoxy17methylmorphinan6onemonohydrate

Ejemplares similares