1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone

The six-membered oxacyclo­hexene ring of the title compound, C(13)H(14)N(2)O(2)S, is fused with the benzene ring and the quarternary C atom lies above the plane of the benzene ring by 0.229 (8) Å, whereas the methine C atom (which bears the acetyl substituent) lies below this plane by 0.595 (8) Å. T...

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Autores principales: Kurbanova, Malahat M., Maharramov, Abel M., Novruzova, Aysel B., Gurbanov, Atash V., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089221/
https://www.ncbi.nlm.nih.gov/pubmed/21754464
http://dx.doi.org/10.1107/S1600536811013699
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author Kurbanova, Malahat M.
Maharramov, Abel M.
Novruzova, Aysel B.
Gurbanov, Atash V.
Ng, Seik Weng
author_facet Kurbanova, Malahat M.
Maharramov, Abel M.
Novruzova, Aysel B.
Gurbanov, Atash V.
Ng, Seik Weng
author_sort Kurbanova, Malahat M.
collection PubMed
description The six-membered oxacyclo­hexene ring of the title compound, C(13)H(14)N(2)O(2)S, is fused with the benzene ring and the quarternary C atom lies above the plane of the benzene ring by 0.229 (8) Å, whereas the methine C atom (which bears the acetyl substituent) lies below this plane by 0.595 (8) Å. The oxacyclo­hexene ring is also fused with the sofa-shaped 2,6-diaza­cyclo­hexa­none ring. The methine C atom that belongs to both six-membered rings lies above the mean plane of the other five atoms (r.m.s. deviation = 0.077 Å) by 0.759 (5) Å. In the crystal, N—H⋯S hydrogen bonds link adjacent mol­ecules into a linear chain.
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spelling pubmed-30892212011-07-13 1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone Kurbanova, Malahat M. Maharramov, Abel M. Novruzova, Aysel B. Gurbanov, Atash V. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The six-membered oxacyclo­hexene ring of the title compound, C(13)H(14)N(2)O(2)S, is fused with the benzene ring and the quarternary C atom lies above the plane of the benzene ring by 0.229 (8) Å, whereas the methine C atom (which bears the acetyl substituent) lies below this plane by 0.595 (8) Å. The oxacyclo­hexene ring is also fused with the sofa-shaped 2,6-diaza­cyclo­hexa­none ring. The methine C atom that belongs to both six-membered rings lies above the mean plane of the other five atoms (r.m.s. deviation = 0.077 Å) by 0.759 (5) Å. In the crystal, N—H⋯S hydrogen bonds link adjacent mol­ecules into a linear chain. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089221/ /pubmed/21754464 http://dx.doi.org/10.1107/S1600536811013699 Text en © Kurbanova et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kurbanova, Malahat M.
Maharramov, Abel M.
Novruzova, Aysel B.
Gurbanov, Atash V.
Ng, Seik Weng
1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
title 1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
title_full 1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
title_fullStr 1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
title_full_unstemmed 1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
title_short 1-(9-Methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
title_sort 1-(9-methyl-11-sulfanyl­idene-8-oxa-10,12-diaza­tricyclo­[7.3.1.0(2,7)]trideca-2,4,6-trien-13-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089221/
https://www.ncbi.nlm.nih.gov/pubmed/21754464
http://dx.doi.org/10.1107/S1600536811013699
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