[Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate

In the title half-sandwich complex, [RuCl(η(6)-C(12)H(18))(C(10)H(9)N(3))]PF(6)·CH(2)Cl(2), the ruthenium(II) ion is four-coordinated by a chloro, a hexa­methyl­benzene and a bidentate N,N′-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N—H group forms a hydrogen bond with the chl...

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Detalles Bibliográficos
Autores principales: Gupta, Gajendra, Therrien, Bruno, Kim, Jinkwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089226/
https://www.ncbi.nlm.nih.gov/pubmed/21754285
http://dx.doi.org/10.1107/S1600536811011640
Descripción
Sumario:In the title half-sandwich complex, [RuCl(η(6)-C(12)H(18))(C(10)H(9)N(3))]PF(6)·CH(2)Cl(2), the ruthenium(II) ion is four-coordinated by a chloro, a hexa­methyl­benzene and a bidentate N,N′-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N—H group forms a hydrogen bond with the chloro ligand of a neighbouring complex, thus forming chains along the b axis. Weak inter­molecular C—H⋯F and C—H⋯ Cl contacts are also observed.

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