[Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate

In the title half-sandwich complex, [RuCl(η(6)-C(12)H(18))(C(10)H(9)N(3))]PF(6)·CH(2)Cl(2), the ruthenium(II) ion is four-coordinated by a chloro, a hexa­methyl­benzene and a bidentate N,N′-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N—H group forms a hydrogen bond with the chl...

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Detalles Bibliográficos
Autores principales: Gupta, Gajendra, Therrien, Bruno, Kim, Jinkwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089226/
https://www.ncbi.nlm.nih.gov/pubmed/21754285
http://dx.doi.org/10.1107/S1600536811011640
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author Gupta, Gajendra
Therrien, Bruno
Kim, Jinkwon
author_facet Gupta, Gajendra
Therrien, Bruno
Kim, Jinkwon
author_sort Gupta, Gajendra
collection PubMed
description In the title half-sandwich complex, [RuCl(η(6)-C(12)H(18))(C(10)H(9)N(3))]PF(6)·CH(2)Cl(2), the ruthenium(II) ion is four-coordinated by a chloro, a hexa­methyl­benzene and a bidentate N,N′-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N—H group forms a hydrogen bond with the chloro ligand of a neighbouring complex, thus forming chains along the b axis. Weak inter­molecular C—H⋯F and C—H⋯ Cl contacts are also observed.
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spelling pubmed-30892262011-07-13 [Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate Gupta, Gajendra Therrien, Bruno Kim, Jinkwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title half-sandwich complex, [RuCl(η(6)-C(12)H(18))(C(10)H(9)N(3))]PF(6)·CH(2)Cl(2), the ruthenium(II) ion is four-coordinated by a chloro, a hexa­methyl­benzene and a bidentate N,N′-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N—H group forms a hydrogen bond with the chloro ligand of a neighbouring complex, thus forming chains along the b axis. Weak inter­molecular C—H⋯F and C—H⋯ Cl contacts are also observed. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089226/ /pubmed/21754285 http://dx.doi.org/10.1107/S1600536811011640 Text en © Gupta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gupta, Gajendra
Therrien, Bruno
Kim, Jinkwon
[Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate
title [Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate
title_full [Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate
title_fullStr [Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate
title_full_unstemmed [Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate
title_short [Bis­(2-pyrid­yl-κN)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate dichloro­methane solvate
title_sort [bis­(2-pyrid­yl-κn)amine]chlorido(η(6)-hexa­methyl­benzene)­ruthenium(ii) hexa­fluorido­phosphate dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089226/
https://www.ncbi.nlm.nih.gov/pubmed/21754285
http://dx.doi.org/10.1107/S1600536811011640
work_keys_str_mv AT guptagajendra bis2pyridylknaminechloridoē6hexamethylbenzenerutheniumiihexafluoridophosphatedichloromethanesolvate
AT therrienbruno bis2pyridylknaminechloridoē6hexamethylbenzenerutheniumiihexafluoridophosphatedichloromethanesolvate
AT kimjinkwon bis2pyridylknaminechloridoē6hexamethylbenzenerutheniumiihexafluoridophosphatedichloromethanesolvate

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