2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine

In the title compound, C(21)H(16)F(2)N(2), the seven-membered 1,4-diazepine ring of the benzodiazepine ring system adopts a distorted-boat conformation. The benzene ring of this system makes dihedral angles of 18.6 (2) and 78.8 (2)° with those of two fluoro­phenyl substituents. In the crystal, inver...

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Detalles Bibliográficos
Autores principales: Baktır, Zeliha, Akkurt, Mehmet, Samshuddin, S., Narayana, B., Yathirajan, H. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089231/
https://www.ncbi.nlm.nih.gov/pubmed/21754550
http://dx.doi.org/10.1107/S1600536811015455
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author Baktır, Zeliha
Akkurt, Mehmet
Samshuddin, S.
Narayana, B.
Yathirajan, H. S.
author_facet Baktır, Zeliha
Akkurt, Mehmet
Samshuddin, S.
Narayana, B.
Yathirajan, H. S.
author_sort Baktır, Zeliha
collection PubMed
description In the title compound, C(21)H(16)F(2)N(2), the seven-membered 1,4-diazepine ring of the benzodiazepine ring system adopts a distorted-boat conformation. The benzene ring of this system makes dihedral angles of 18.6 (2) and 78.8 (2)° with those of two fluoro­phenyl substituents. In the crystal, inversion dimers linked by two weak C—H⋯F hydrogen bonds generate R (2) (2)(20) ring motifs. There are also weak N—H⋯π and C—H⋯π inter­actions.
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spelling pubmed-30892312011-07-13 2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine Baktır, Zeliha Akkurt, Mehmet Samshuddin, S. Narayana, B. Yathirajan, H. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(16)F(2)N(2), the seven-membered 1,4-diazepine ring of the benzodiazepine ring system adopts a distorted-boat conformation. The benzene ring of this system makes dihedral angles of 18.6 (2) and 78.8 (2)° with those of two fluoro­phenyl substituents. In the crystal, inversion dimers linked by two weak C—H⋯F hydrogen bonds generate R (2) (2)(20) ring motifs. There are also weak N—H⋯π and C—H⋯π inter­actions. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089231/ /pubmed/21754550 http://dx.doi.org/10.1107/S1600536811015455 Text en © Baktır et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Baktır, Zeliha
Akkurt, Mehmet
Samshuddin, S.
Narayana, B.
Yathirajan, H. S.
2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine
title 2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine
title_full 2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine
title_fullStr 2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine
title_full_unstemmed 2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine
title_short 2,4-Bis(4-fluoro­phen­yl)-2,3-dihydro-1H-1,5-benzodiazepine
title_sort 2,4-bis(4-fluoro­phen­yl)-2,3-dihydro-1h-1,5-benzodiazepine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089231/
https://www.ncbi.nlm.nih.gov/pubmed/21754550
http://dx.doi.org/10.1107/S1600536811015455
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AT samshuddins 24bis4fluorophenyl23dihydro1h15benzodiazepine
AT narayanab 24bis4fluorophenyl23dihydro1h15benzodiazepine
AT yathirajanhs 24bis4fluorophenyl23dihydro1h15benzodiazepine

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