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[N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate
In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octahedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine ligand. The uncoordinated so...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089232/ https://www.ncbi.nlm.nih.gov/pubmed/21754271 http://dx.doi.org/10.1107/S1600536811011810 |
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author | Wu, Gui-Ling Ou, Chun-Ping Wang, Feng Zhang, Jian-Ming Lan, She-Min |
author_facet | Wu, Gui-Ling Ou, Chun-Ping Wang, Feng Zhang, Jian-Ming Lan, She-Min |
author_sort | Wu, Gui-Ling |
collection | PubMed |
description | In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octahedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol molecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π stacking interactions between the imidazol rings and between the imidazol and benzene rings [centroid–centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network. |
format | Text |
id | pubmed-3089232 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892322011-07-13 [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate Wu, Gui-Ling Ou, Chun-Ping Wang, Feng Zhang, Jian-Ming Lan, She-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octahedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol molecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π stacking interactions between the imidazol rings and between the imidazol and benzene rings [centroid–centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089232/ /pubmed/21754271 http://dx.doi.org/10.1107/S1600536811011810 Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Gui-Ling Ou, Chun-Ping Wang, Feng Zhang, Jian-Ming Lan, She-Min [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate |
title | [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate |
title_full | [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate |
title_fullStr | [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate |
title_full_unstemmed | [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate |
title_short | [N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate |
title_sort | [n,n,n′,n′-tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(ii) bis(perchlorate) methanol solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089232/ https://www.ncbi.nlm.nih.gov/pubmed/21754271 http://dx.doi.org/10.1107/S1600536811011810 |
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