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[N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate

In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa­hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetra­kis­(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine ligand. The uncoordinated so...

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Autores principales: Wu, Gui-Ling, Ou, Chun-Ping, Wang, Feng, Zhang, Jian-Ming, Lan, She-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089232/
https://www.ncbi.nlm.nih.gov/pubmed/21754271
http://dx.doi.org/10.1107/S1600536811011810
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author Wu, Gui-Ling
Ou, Chun-Ping
Wang, Feng
Zhang, Jian-Ming
Lan, She-Min
author_facet Wu, Gui-Ling
Ou, Chun-Ping
Wang, Feng
Zhang, Jian-Ming
Lan, She-Min
author_sort Wu, Gui-Ling
collection PubMed
description In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa­hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetra­kis­(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol­ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π stacking inter­actions between the imidazol rings and between the imidazol and benzene rings [centroid–centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network.
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spelling pubmed-30892322011-07-13 [N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate Wu, Gui-Ling Ou, Chun-Ping Wang, Feng Zhang, Jian-Ming Lan, She-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa­hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetra­kis­(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol­ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π stacking inter­actions between the imidazol rings and between the imidazol and benzene rings [centroid–centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089232/ /pubmed/21754271 http://dx.doi.org/10.1107/S1600536811011810 Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Gui-Ling
Ou, Chun-Ping
Wang, Feng
Zhang, Jian-Ming
Lan, She-Min
[N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate
title [N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate
title_full [N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate
title_fullStr [N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate
title_full_unstemmed [N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate
title_short [N,N,N′,N′-Tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(II) bis­(perchlorate) methanol solvate
title_sort [n,n,n′,n′-tetra­kis(benzimidazol-2-ylmeth­yl)cyclo­hexane-1,2-trans-diamine]­iron(ii) bis­(perchlorate) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089232/
https://www.ncbi.nlm.nih.gov/pubmed/21754271
http://dx.doi.org/10.1107/S1600536811011810
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