Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate

In the title compound, [CoCl(2)(C(13)H(20)N(4))]·H(2)O, the Co(II) atom lies on a mirror plane and is four-coordinated by two N atoms of the imidazole ligand and two Cl atoms in a distorted tetra­hedral arrangement. The water mol­ecule participates in the formation of hydrogen bonds, resulting in a...

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Autores principales: Qian, Xiao-Min, Luo, Yang-Hui, Li, Jin-Feng, Mao, Shu-Lin, Gao, Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089236/
https://www.ncbi.nlm.nih.gov/pubmed/21754302
http://dx.doi.org/10.1107/S1600536811011032
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author Qian, Xiao-Min
Luo, Yang-Hui
Li, Jin-Feng
Mao, Shu-Lin
Gao, Ge
author_facet Qian, Xiao-Min
Luo, Yang-Hui
Li, Jin-Feng
Mao, Shu-Lin
Gao, Ge
author_sort Qian, Xiao-Min
collection PubMed
description In the title compound, [CoCl(2)(C(13)H(20)N(4))]·H(2)O, the Co(II) atom lies on a mirror plane and is four-coordinated by two N atoms of the imidazole ligand and two Cl atoms in a distorted tetra­hedral arrangement. The water mol­ecule participates in the formation of hydrogen bonds, resulting in a three dimensional network involving the Cl atoms and the NH groups. The terminal C atom of the ethyl group is disordered over two sites of equal occupancy.
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spelling pubmed-30892362011-07-13 Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate Qian, Xiao-Min Luo, Yang-Hui Li, Jin-Feng Mao, Shu-Lin Gao, Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(13)H(20)N(4))]·H(2)O, the Co(II) atom lies on a mirror plane and is four-coordinated by two N atoms of the imidazole ligand and two Cl atoms in a distorted tetra­hedral arrangement. The water mol­ecule participates in the formation of hydrogen bonds, resulting in a three dimensional network involving the Cl atoms and the NH groups. The terminal C atom of the ethyl group is disordered over two sites of equal occupancy. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089236/ /pubmed/21754302 http://dx.doi.org/10.1107/S1600536811011032 Text en © Qian et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qian, Xiao-Min
Luo, Yang-Hui
Li, Jin-Feng
Mao, Shu-Lin
Gao, Ge
Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate
title Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate
title_full Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate
title_fullStr Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate
title_full_unstemmed Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate
title_short Dichlorido[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­cobalt(II) monohydrate
title_sort dichlorido[bis­(2-ethyl-5-methyl-1h-imidazol-4-yl-κn (3))methane]­cobalt(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089236/
https://www.ncbi.nlm.nih.gov/pubmed/21754302
http://dx.doi.org/10.1107/S1600536811011032
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