RbSn(2)(PO(4))(3), a NASICON-type phosphate

The title compound, rubidium ditin(IV) tris­(phosphate), RbSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates and crystallizes in the space group R [Image: see text]. The structure is composed of PO(4) tetra­hedra (1 symmetry) and two slightly distorted SnO(6) octa­hedra, both with 3....

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Detalles Bibliográficos
Autores principales: Zhao, Dan, Li, FeiFei, Qiu, Shen, Jiao, Jiali, Ren, Junran
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089237/
https://www.ncbi.nlm.nih.gov/pubmed/21754258
http://dx.doi.org/10.1107/S1600536811014310
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author Zhao, Dan
Li, FeiFei
Qiu, Shen
Jiao, Jiali
Ren, Junran
author_facet Zhao, Dan
Li, FeiFei
Qiu, Shen
Jiao, Jiali
Ren, Junran
author_sort Zhao, Dan
collection PubMed
description The title compound, rubidium ditin(IV) tris­(phosphate), RbSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates and crystallizes in the space group R [Image: see text]. The structure is composed of PO(4) tetra­hedra (1 symmetry) and two slightly distorted SnO(6) octa­hedra, both with 3. symmetry, which are inter­linked through corner-sharing O atoms to form a (3) (∞)[Sn(2)(PO(4))(3)](−) framework. The Rb(+) cations are located on threefold inversion axes in the voids of this framework and exhibit a coordination number of 12. The crystal studied was twinned by merohedry with a component ratio of 0.503:0.497.
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spelling pubmed-30892372011-07-13 RbSn(2)(PO(4))(3), a NASICON-type phosphate Zhao, Dan Li, FeiFei Qiu, Shen Jiao, Jiali Ren, Junran Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, rubidium ditin(IV) tris­(phosphate), RbSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates and crystallizes in the space group R [Image: see text]. The structure is composed of PO(4) tetra­hedra (1 symmetry) and two slightly distorted SnO(6) octa­hedra, both with 3. symmetry, which are inter­linked through corner-sharing O atoms to form a (3) (∞)[Sn(2)(PO(4))(3)](−) framework. The Rb(+) cations are located on threefold inversion axes in the voids of this framework and exhibit a coordination number of 12. The crystal studied was twinned by merohedry with a component ratio of 0.503:0.497. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089237/ /pubmed/21754258 http://dx.doi.org/10.1107/S1600536811014310 Text en © Zhao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhao, Dan
Li, FeiFei
Qiu, Shen
Jiao, Jiali
Ren, Junran
RbSn(2)(PO(4))(3), a NASICON-type phosphate
title RbSn(2)(PO(4))(3), a NASICON-type phosphate
title_full RbSn(2)(PO(4))(3), a NASICON-type phosphate
title_fullStr RbSn(2)(PO(4))(3), a NASICON-type phosphate
title_full_unstemmed RbSn(2)(PO(4))(3), a NASICON-type phosphate
title_short RbSn(2)(PO(4))(3), a NASICON-type phosphate
title_sort rbsn(2)(po(4))(3), a nasicon-type phosphate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089237/
https://www.ncbi.nlm.nih.gov/pubmed/21754258
http://dx.doi.org/10.1107/S1600536811014310
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AT lifeifei rbsn2po43anasicontypephosphate
AT qiushen rbsn2po43anasicontypephosphate
AT jiaojiali rbsn2po43anasicontypephosphate
AT renjunran rbsn2po43anasicontypephosphate

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