4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate

In the crystal structure of the title compound, C(18)H(19)N(2)O(+)·BF(4) (−), bifurcated N—H⋯(F,F) hydrogen bonds link the protonated 4′-morpholine­methyl­biphenyl-2-carbonitrile cations and slightly distorted tetra­fluoro­borate anions. π–π inter­actions [centroid–centroid distance = 3.805 (3) Å] h...

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Detalles Bibliográficos
Autores principales: Li, Xiu-juan, Huang, Xian-gang, Li, Kang-jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089242/
https://www.ncbi.nlm.nih.gov/pubmed/21754387
http://dx.doi.org/10.1107/S160053681101186X
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author Li, Xiu-juan
Huang, Xian-gang
Li, Kang-jun
author_facet Li, Xiu-juan
Huang, Xian-gang
Li, Kang-jun
author_sort Li, Xiu-juan
collection PubMed
description In the crystal structure of the title compound, C(18)H(19)N(2)O(+)·BF(4) (−), bifurcated N—H⋯(F,F) hydrogen bonds link the protonated 4′-morpholine­methyl­biphenyl-2-carbonitrile cations and slightly distorted tetra­fluoro­borate anions. π–π inter­actions [centroid–centroid distance = 3.805 (3) Å] help to consolidate the packing. The dihedral angle between the benzene rings in the cation is 57.24 (11)°.
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spelling pubmed-30892422011-07-13 4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate Li, Xiu-juan Huang, Xian-gang Li, Kang-jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(18)H(19)N(2)O(+)·BF(4) (−), bifurcated N—H⋯(F,F) hydrogen bonds link the protonated 4′-morpholine­methyl­biphenyl-2-carbonitrile cations and slightly distorted tetra­fluoro­borate anions. π–π inter­actions [centroid–centroid distance = 3.805 (3) Å] help to consolidate the packing. The dihedral angle between the benzene rings in the cation is 57.24 (11)°. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089242/ /pubmed/21754387 http://dx.doi.org/10.1107/S160053681101186X Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xiu-juan
Huang, Xian-gang
Li, Kang-jun
4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
title 4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
title_full 4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
title_fullStr 4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
title_full_unstemmed 4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
title_short 4-[(2′-Cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
title_sort 4-[(2′-cyano­biphen­yl-4-yl)meth­yl]morpholin-4-ium tetra­fluoridoborate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089242/
https://www.ncbi.nlm.nih.gov/pubmed/21754387
http://dx.doi.org/10.1107/S160053681101186X
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AT likangjun 42cyanobiphenyl4ylmethylmorpholin4iumtetrafluoridoborate

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