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(2-Methyl-4-oxo-4H-pyran-3-olato-κ(2) O (3),O (4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1)
In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the Cu(I) atom 0.451 (5) Å out of the plane. The Cu(I) atom has a distorted tetrahedral coordination. The O—Cu—O angle is 80.07 (8)° and the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089247/ https://www.ncbi.nlm.nih.gov/pubmed/21754306 http://dx.doi.org/10.1107/S1600536811011470 |
| _version_ | 1782203012277600256 |
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| author | Muller, Fabian M. A. Muller, Theunis J. Steyl, Gideon |
| author_facet | Muller, Fabian M. A. Muller, Theunis J. Steyl, Gideon |
| author_sort | Muller, Fabian M. A. |
| collection | PubMed |
| description | In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the Cu(I) atom 0.451 (5) Å out of the plane. The Cu(I) atom has a distorted tetrahedral coordination. The O—Cu—O angle is 80.07 (8)° and the P—Cu—P angle is 123.49 (3)°. The crystal packing is stablized by intramolecular C—H⋯O interactions and intermolecular C—H⋯O and O—H⋯O interactions. |
| format | Text |
| id | pubmed-3089247 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30892472011-07-13 (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2) O (3),O (4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) Muller, Fabian M. A. Muller, Theunis J. Steyl, Gideon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the Cu(I) atom 0.451 (5) Å out of the plane. The Cu(I) atom has a distorted tetrahedral coordination. The O—Cu—O angle is 80.07 (8)° and the P—Cu—P angle is 123.49 (3)°. The crystal packing is stablized by intramolecular C—H⋯O interactions and intermolecular C—H⋯O and O—H⋯O interactions. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089247/ /pubmed/21754306 http://dx.doi.org/10.1107/S1600536811011470 Text en © Muller et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Muller, Fabian M. A. Muller, Theunis J. Steyl, Gideon (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2) O (3),O (4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) |
| title | (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2)
O
(3),O
(4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) |
| title_full | (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2)
O
(3),O
(4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) |
| title_fullStr | (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2)
O
(3),O
(4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) |
| title_full_unstemmed | (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2)
O
(3),O
(4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) |
| title_short | (2-Methyl-4-oxo-4H-pyran-3-olato-κ(2)
O
(3),O
(4))bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1) |
| title_sort | (2-methyl-4-oxo-4h-pyran-3-olato-κ(2)
o
(3),o
(4))bis(triphenylphosphane-κp)copper(i)–triphenylphosphane–methanol (1/1/1) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089247/ https://www.ncbi.nlm.nih.gov/pubmed/21754306 http://dx.doi.org/10.1107/S1600536811011470 |
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