Cargando…
Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato]
The structure of the title compound, [Li(BF(4))(CH(3)CN)](n), consists of a layered arrangement parallel to (100) in which the Li(+) cations are coordinated by three F atoms from three tetrafluoridoborate (BF(4) (−)) anions and an N atom from an acetonitrile molecule. The BF(4) (−) anion is coordi...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089248/ https://www.ncbi.nlm.nih.gov/pubmed/21754284 http://dx.doi.org/10.1107/S1600536811012141 |
| _version_ | 1782203012516675584 |
|---|---|
| author | Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. |
| author_facet | Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. |
| author_sort | Seo, Daniel M. |
| collection | PubMed |
| description | The structure of the title compound, [Li(BF(4))(CH(3)CN)](n), consists of a layered arrangement parallel to (100) in which the Li(+) cations are coordinated by three F atoms from three tetrafluoridoborate (BF(4) (−)) anions and an N atom from an acetonitrile molecule. The BF(4) (−) anion is coordinated to three different Li(+) cations though three F atoms. The structure can be described as being built from vertex-shared BF(4) and LiF(3)(NCCH(3)) tetrahedra. These tetrahedra reside around a crystallographic inversion center and form 8-membered rings. |
| format | Text |
| id | pubmed-3089248 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30892482011-07-13 Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Li(BF(4))(CH(3)CN)](n), consists of a layered arrangement parallel to (100) in which the Li(+) cations are coordinated by three F atoms from three tetrafluoridoborate (BF(4) (−)) anions and an N atom from an acetonitrile molecule. The BF(4) (−) anion is coordinated to three different Li(+) cations though three F atoms. The structure can be described as being built from vertex-shared BF(4) and LiF(3)(NCCH(3)) tetrahedra. These tetrahedra reside around a crystallographic inversion center and form 8-membered rings. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089248/ /pubmed/21754284 http://dx.doi.org/10.1107/S1600536811012141 Text en © Seo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] |
| title | Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] |
| title_full | Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] |
| title_fullStr | Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] |
| title_full_unstemmed | Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] |
| title_short | Poly[[(acetonitrile)lithium(I)]-μ(3)-tetrafluoridoborato] |
| title_sort | poly[[(acetonitrile)lithium(i)]-μ(3)-tetrafluoridoborato] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089248/ https://www.ncbi.nlm.nih.gov/pubmed/21754284 http://dx.doi.org/10.1107/S1600536811012141 |
| work_keys_str_mv | AT seodanielm polyacetonitrilelithiumim3tetrafluoridoborato AT boylepauld polyacetonitrilelithiumim3tetrafluoridoborato AT hendersonwesleya polyacetonitrilelithiumim3tetrafluoridoborato |