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1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate)
The title compound, C(15)H(20)N(2)O(2) (2+)·2PF(6) (−), was prepared by anion exchange of two bromide ions in the ionic liquid 2,2′-bis-(pyridinium-1-ylmethyl)-propane-1,3-diol dibromide with potassium hexafluorophosphate. The two pyridine rings are planar (r.m.s. deviations = 0.008 and 0.00440 Å...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089249/ https://www.ncbi.nlm.nih.gov/pubmed/21754422 http://dx.doi.org/10.1107/S1600536811013080 |
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author | Yuan, Ai-lin Zheng, Chun-ling Zhuang, Ling-hua Wang, Chang-sheng Wang, Guo-wei |
author_facet | Yuan, Ai-lin Zheng, Chun-ling Zhuang, Ling-hua Wang, Chang-sheng Wang, Guo-wei |
author_sort | Yuan, Ai-lin |
collection | PubMed |
description | The title compound, C(15)H(20)N(2)O(2) (2+)·2PF(6) (−), was prepared by anion exchange of two bromide ions in the ionic liquid 2,2′-bis-(pyridinium-1-ylmethyl)-propane-1,3-diol dibromide with potassium hexafluorophosphate. The two pyridine rings are planar (r.m.s. deviations = 0.008 and 0.00440 Å) and make a dihedral angle of 44.0 (2)°. Intermolecular O—H⋯F and C—H⋯F interactions occur. The four F atoms in each anion were refined as disordered over two sets of sites with an occupancy ration of 0.700 (19):0.300 (19). |
format | Text |
id | pubmed-3089249 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892492011-07-13 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) Yuan, Ai-lin Zheng, Chun-ling Zhuang, Ling-hua Wang, Chang-sheng Wang, Guo-wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)N(2)O(2) (2+)·2PF(6) (−), was prepared by anion exchange of two bromide ions in the ionic liquid 2,2′-bis-(pyridinium-1-ylmethyl)-propane-1,3-diol dibromide with potassium hexafluorophosphate. The two pyridine rings are planar (r.m.s. deviations = 0.008 and 0.00440 Å) and make a dihedral angle of 44.0 (2)°. Intermolecular O—H⋯F and C—H⋯F interactions occur. The four F atoms in each anion were refined as disordered over two sets of sites with an occupancy ration of 0.700 (19):0.300 (19). International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089249/ /pubmed/21754422 http://dx.doi.org/10.1107/S1600536811013080 Text en © Yuan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yuan, Ai-lin Zheng, Chun-ling Zhuang, Ling-hua Wang, Chang-sheng Wang, Guo-wei 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
title | 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
title_full | 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
title_fullStr | 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
title_full_unstemmed | 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
title_short | 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
title_sort | 1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis(hexafluorophosphate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089249/ https://www.ncbi.nlm.nih.gov/pubmed/21754422 http://dx.doi.org/10.1107/S1600536811013080 |
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