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1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)

The title compound, C(15)H(20)N(2)O(2) (2+)·2PF(6) (−), was prepared by anion exchange of two bromide ions in the ionic liquid 2,2′-bis-(pyridinium-1-ylmeth­yl)-propane-1,3-diol dibromide with potassium hexa­fluoro­phosphate. The two pyridine rings are planar (r.m.s. deviations = 0.008 and 0.00440 Å...

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Detalles Bibliográficos
Autores principales: Yuan, Ai-lin, Zheng, Chun-ling, Zhuang, Ling-hua, Wang, Chang-sheng, Wang, Guo-wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089249/
https://www.ncbi.nlm.nih.gov/pubmed/21754422
http://dx.doi.org/10.1107/S1600536811013080
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author Yuan, Ai-lin
Zheng, Chun-ling
Zhuang, Ling-hua
Wang, Chang-sheng
Wang, Guo-wei
author_facet Yuan, Ai-lin
Zheng, Chun-ling
Zhuang, Ling-hua
Wang, Chang-sheng
Wang, Guo-wei
author_sort Yuan, Ai-lin
collection PubMed
description The title compound, C(15)H(20)N(2)O(2) (2+)·2PF(6) (−), was prepared by anion exchange of two bromide ions in the ionic liquid 2,2′-bis-(pyridinium-1-ylmeth­yl)-propane-1,3-diol dibromide with potassium hexa­fluoro­phosphate. The two pyridine rings are planar (r.m.s. deviations = 0.008 and 0.00440 Å) and make a dihedral angle of 44.0 (2)°. Intermolecular O—H⋯F and C—H⋯F interactions occur. The four F atoms in each anion were refined as disordered over two sets of sites with an occupancy ration of 0.700 (19):0.300 (19).
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spelling pubmed-30892492011-07-13 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate) Yuan, Ai-lin Zheng, Chun-ling Zhuang, Ling-hua Wang, Chang-sheng Wang, Guo-wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)N(2)O(2) (2+)·2PF(6) (−), was prepared by anion exchange of two bromide ions in the ionic liquid 2,2′-bis-(pyridinium-1-ylmeth­yl)-propane-1,3-diol dibromide with potassium hexa­fluoro­phosphate. The two pyridine rings are planar (r.m.s. deviations = 0.008 and 0.00440 Å) and make a dihedral angle of 44.0 (2)°. Intermolecular O—H⋯F and C—H⋯F interactions occur. The four F atoms in each anion were refined as disordered over two sets of sites with an occupancy ration of 0.700 (19):0.300 (19). International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089249/ /pubmed/21754422 http://dx.doi.org/10.1107/S1600536811013080 Text en © Yuan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yuan, Ai-lin
Zheng, Chun-ling
Zhuang, Ling-hua
Wang, Chang-sheng
Wang, Guo-wei
1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
title 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
title_full 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
title_fullStr 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
title_full_unstemmed 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
title_short 1,1′-[(1,3-Dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
title_sort 1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylene]dipyridinium bis­(hexa­fluoro­phosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089249/
https://www.ncbi.nlm.nih.gov/pubmed/21754422
http://dx.doi.org/10.1107/S1600536811013080
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