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Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
In the title compound, [Cu(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the coordination around the Cu(II) atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 2.008 (3) and 2.019 (3) Å] and two O atoms from 3-fluorobenzoate ligands a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089262/ https://www.ncbi.nlm.nih.gov/pubmed/21754295 http://dx.doi.org/10.1107/S1600536811012220 |
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author | Yin, Xin |
author_facet | Yin, Xin |
author_sort | Yin, Xin |
collection | PubMed |
description | In the title compound, [Cu(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the coordination around the Cu(II) atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 2.008 (3) and 2.019 (3) Å] and two O atoms from 3-fluorobenzoate ligands and a water molecule [Cu—O = 1.950 (2) and 1.978 (2) Å]. One O atom from another 3-fluorobenzoate ligand occupies the apical positon [Cu—O = 2.210 (2) Å]. Hydrogen bonds occur between coordinated water molecules and benzoate ligands, while O—H⋯O, C—H⋯O, C—H⋯F and π–π stacking [centroid–centroid distance = 3.731 (2) Å] interactions consolidate the crystal packing. |
format | Text |
id | pubmed-3089262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892622011-07-13 Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Yin, Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the coordination around the Cu(II) atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 2.008 (3) and 2.019 (3) Å] and two O atoms from 3-fluorobenzoate ligands and a water molecule [Cu—O = 1.950 (2) and 1.978 (2) Å]. One O atom from another 3-fluorobenzoate ligand occupies the apical positon [Cu—O = 2.210 (2) Å]. Hydrogen bonds occur between coordinated water molecules and benzoate ligands, while O—H⋯O, C—H⋯O, C—H⋯F and π–π stacking [centroid–centroid distance = 3.731 (2) Å] interactions consolidate the crystal packing. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089262/ /pubmed/21754295 http://dx.doi.org/10.1107/S1600536811012220 Text en © Xin Yin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yin, Xin Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | aquabis(3-fluorobenzoato-κo)(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089262/ https://www.ncbi.nlm.nih.gov/pubmed/21754295 http://dx.doi.org/10.1107/S1600536811012220 |
work_keys_str_mv | AT yinxin aquabis3fluorobenzoatoko110phenanthrolinek2nncopperii |