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Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title compound, [Cu(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the coordination around the Cu(II) atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 2.008 (3) and 2.019 (3) Å] and two O atoms from 3-fluoro­benzoate ligands a...

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Detalles Bibliográficos
Autor principal: Yin, Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089262/
https://www.ncbi.nlm.nih.gov/pubmed/21754295
http://dx.doi.org/10.1107/S1600536811012220
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author Yin, Xin
author_facet Yin, Xin
author_sort Yin, Xin
collection PubMed
description In the title compound, [Cu(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the coordination around the Cu(II) atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 2.008 (3) and 2.019 (3) Å] and two O atoms from 3-fluoro­benzoate ligands and a water mol­ecule [Cu—O = 1.950 (2) and 1.978 (2) Å]. One O atom from another 3-fluoro­benzoate ligand occupies the apical positon [Cu—O = 2.210 (2) Å]. Hydrogen bonds occur between coordinated water mol­ecules and benzoate ligands, while O—H⋯O, C—H⋯O, C—H⋯F and π–π stacking [centroid–centroid distance = 3.731 (2) Å] inter­actions consolidate the crystal packing.
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spelling pubmed-30892622011-07-13 Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Yin, Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the coordination around the Cu(II) atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 2.008 (3) and 2.019 (3) Å] and two O atoms from 3-fluoro­benzoate ligands and a water mol­ecule [Cu—O = 1.950 (2) and 1.978 (2) Å]. One O atom from another 3-fluoro­benzoate ligand occupies the apical positon [Cu—O = 2.210 (2) Å]. Hydrogen bonds occur between coordinated water mol­ecules and benzoate ligands, while O—H⋯O, C—H⋯O, C—H⋯F and π–π stacking [centroid–centroid distance = 3.731 (2) Å] inter­actions consolidate the crystal packing. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089262/ /pubmed/21754295 http://dx.doi.org/10.1107/S1600536811012220 Text en © Xin Yin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Xin
Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Aqua­bis­(3-fluoro­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort aqua­bis­(3-fluoro­benzoato-κo)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089262/
https://www.ncbi.nlm.nih.gov/pubmed/21754295
http://dx.doi.org/10.1107/S1600536811012220
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