(Benzyl phenyl sulfoxide-κO)dichloridodiphenyl­tin(IV)

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal–bipyramidal coordination environment, with a mean Sn—C distance of 2.121 (9) Å and with Sn—O = 2.331 (2) Å. The Sn(IV) atom is displaced by 0.169 (2) Å from the equatorial C(2)Cl pla...

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Detalles Bibliográficos
Autores principales: Tan, Guo-Xia, Zhang, Chang-Fa, Liu, Xi-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089264/
https://www.ncbi.nlm.nih.gov/pubmed/21754340
http://dx.doi.org/10.1107/S1600536811014474
Descripción
Sumario:The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal–bipyramidal coordination environment, with a mean Sn—C distance of 2.121 (9) Å and with Sn—O = 2.331 (2) Å. The Sn(IV) atom is displaced by 0.169 (2) Å from the equatorial C(2)Cl plane towards the direction of the second axially bonded Cl atom.

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