Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate

In the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imid­azole-5-carboxyl­ato anions and two water O atoms in an octa­hedral environment, Each 4-carbox...

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Detalles Bibliográficos
Autores principales: Hao, Cheng-Jun, Xie, Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089267/
https://www.ncbi.nlm.nih.gov/pubmed/21754307
http://dx.doi.org/10.1107/S1600536811012992
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author Hao, Cheng-Jun
Xie, Hui
author_facet Hao, Cheng-Jun
Xie, Hui
author_sort Hao, Cheng-Jun
collection PubMed
description In the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imid­azole-5-carboxyl­ato anions and two water O atoms in an octa­hedral environment, Each 4-carboxy-2-ethyl-1H-imid­azole-5-carboxyl­ato ligand adopts a bidentate chelating mode to the Zn(II) ion, forming two five-membered metalla rings. In the crystal, a two-dimensional framework parallel to (010) is formed by N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-30892672011-07-13 Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate Hao, Cheng-Jun Xie, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imid­azole-5-carboxyl­ato anions and two water O atoms in an octa­hedral environment, Each 4-carboxy-2-ethyl-1H-imid­azole-5-carboxyl­ato ligand adopts a bidentate chelating mode to the Zn(II) ion, forming two five-membered metalla rings. In the crystal, a two-dimensional framework parallel to (010) is formed by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089267/ /pubmed/21754307 http://dx.doi.org/10.1107/S1600536811012992 Text en © Hao and Xie 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Cheng-Jun
Xie, Hui
Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate
title Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate
title_full Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate
title_fullStr Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate
title_full_unstemmed Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate
title_short Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc N,N-dimethyl­formamide disolvate
title_sort diaqua­bis­(4-carb­oxy-2-ethyl-1h-imidazole-5-carboxyl­ato-κ(2) n (3),o (4))zinc n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089267/
https://www.ncbi.nlm.nih.gov/pubmed/21754307
http://dx.doi.org/10.1107/S1600536811012992
work_keys_str_mv AT haochengjun diaquabis4carboxy2ethyl1himidazole5carboxylatok2n3o4zincnndimethylformamidedisolvate
AT xiehui diaquabis4carboxy2ethyl1himidazole5carboxylatok2n3o4zincnndimethylformamidedisolvate

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