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cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2) O,S]copper(II)
The asymmetric unit of the title compound, [Cu(C(10)H(10)BrN(2)OS)(2)], contains two independent complex molecules with almost identical conformations. Two S and two O atoms form the coordination environment of the Cu atom, resulting in a slightly distorted square-planar coordination. The S atoms a...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089271/ https://www.ncbi.nlm.nih.gov/pubmed/21754354 http://dx.doi.org/10.1107/S1600536811015789 |
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author | Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan |
author_facet | Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan |
author_sort | Binzet, Gün |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cu(C(10)H(10)BrN(2)OS)(2)], contains two independent complex molecules with almost identical conformations. Two S and two O atoms form the coordination environment of the Cu atom, resulting in a slightly distorted square-planar coordination. The S atoms are in a cis configuration. The crystal structure is stabilized by weak intermolecular C—H⋯Br hydrogen-bonding interactions. |
format | Text |
id | pubmed-3089271 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892712011-07-13 cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2) O,S]copper(II) Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(10)H(10)BrN(2)OS)(2)], contains two independent complex molecules with almost identical conformations. Two S and two O atoms form the coordination environment of the Cu atom, resulting in a slightly distorted square-planar coordination. The S atoms are in a cis configuration. The crystal structure is stabilized by weak intermolecular C—H⋯Br hydrogen-bonding interactions. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089271/ /pubmed/21754354 http://dx.doi.org/10.1107/S1600536811015789 Text en © Binzet et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2) O,S]copper(II) |
title |
cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2)
O,S]copper(II) |
title_full |
cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2)
O,S]copper(II) |
title_fullStr |
cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2)
O,S]copper(II) |
title_full_unstemmed |
cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2)
O,S]copper(II) |
title_short |
cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ(2)
O,S]copper(II) |
title_sort | cis-bis[n′-(4-bromobenzoyl)-n,n-dimethylthioureato-κ(2)
o,s]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089271/ https://www.ncbi.nlm.nih.gov/pubmed/21754354 http://dx.doi.org/10.1107/S1600536811015789 |
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