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cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)

The asymmetric unit of the title compound, [Cu(C(10)H(10)BrN(2)OS)(2)], contains two independent complex mol­ecules with almost identical conformations. Two S and two O atoms form the coordination environment of the Cu atom, resulting in a slightly distorted square-planar coordination. The S atoms a...

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Detalles Bibliográficos
Autores principales: Binzet, Gün, Flörke, Ulrich, Külcü, Nevzat, Arslan, Hakan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089271/
https://www.ncbi.nlm.nih.gov/pubmed/21754354
http://dx.doi.org/10.1107/S1600536811015789
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author Binzet, Gün
Flörke, Ulrich
Külcü, Nevzat
Arslan, Hakan
author_facet Binzet, Gün
Flörke, Ulrich
Külcü, Nevzat
Arslan, Hakan
author_sort Binzet, Gün
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(10)H(10)BrN(2)OS)(2)], contains two independent complex mol­ecules with almost identical conformations. Two S and two O atoms form the coordination environment of the Cu atom, resulting in a slightly distorted square-planar coordination. The S atoms are in a cis configuration. The crystal structure is stabilized by weak inter­molecular C—H⋯Br hydrogen-bonding inter­actions.
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spelling pubmed-30892712011-07-13 cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II) Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(10)H(10)BrN(2)OS)(2)], contains two independent complex mol­ecules with almost identical conformations. Two S and two O atoms form the coordination environment of the Cu atom, resulting in a slightly distorted square-planar coordination. The S atoms are in a cis configuration. The crystal structure is stabilized by weak inter­molecular C—H⋯Br hydrogen-bonding inter­actions. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089271/ /pubmed/21754354 http://dx.doi.org/10.1107/S1600536811015789 Text en © Binzet et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Binzet, Gün
Flörke, Ulrich
Külcü, Nevzat
Arslan, Hakan
cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)
title cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)
title_full cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)
title_fullStr cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)
title_full_unstemmed cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)
title_short cis-Bis[N′-(4-bromo­benzo­yl)-N,N-dimethyl­thio­ureato-κ(2) O,S]copper(II)
title_sort cis-bis[n′-(4-bromo­benzo­yl)-n,n-dimethyl­thio­ureato-κ(2) o,s]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089271/
https://www.ncbi.nlm.nih.gov/pubmed/21754354
http://dx.doi.org/10.1107/S1600536811015789
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