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catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxylate...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089278/ https://www.ncbi.nlm.nih.gov/pubmed/21754299 http://dx.doi.org/10.1107/S1600536811012360 |
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author | Zhang, Wenjun Chen, Yanmei Lei, Tao Li, Yahong Li, Wu |
author_facet | Zhang, Wenjun Chen, Yanmei Lei, Tao Li, Yahong Li, Wu |
author_sort | Zhang, Wenjun |
collection | PubMed |
description | The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxylate ligands, two O atoms from another two pyridine-2,5-dicarboxylate ligands and two water O atoms. The Pr(III) ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N—H⋯O and O—H⋯O hydrogen bonds are found in the structure. |
format | Text |
id | pubmed-3089278 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892782011-07-13 catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] Zhang, Wenjun Chen, Yanmei Lei, Tao Li, Yahong Li, Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxylate ligands, two O atoms from another two pyridine-2,5-dicarboxylate ligands and two water O atoms. The Pr(III) ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N—H⋯O and O—H⋯O hydrogen bonds are found in the structure. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089278/ /pubmed/21754299 http://dx.doi.org/10.1107/S1600536811012360 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Wenjun Chen, Yanmei Lei, Tao Li, Yahong Li, Wu catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
title |
catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
title_full |
catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
title_fullStr |
catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
title_full_unstemmed |
catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
title_short |
catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
title_sort | catena-poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(iii)]]-bis(μ-pyridine-2,5-dicarboxylato)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089278/ https://www.ncbi.nlm.nih.gov/pubmed/21754299 http://dx.doi.org/10.1107/S1600536811012360 |
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