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catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]

The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxyl­ate...

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Detalles Bibliográficos
Autores principales: Zhang, Wenjun, Chen, Yanmei, Lei, Tao, Li, Yahong, Li, Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089278/
https://www.ncbi.nlm.nih.gov/pubmed/21754299
http://dx.doi.org/10.1107/S1600536811012360
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author Zhang, Wenjun
Chen, Yanmei
Lei, Tao
Li, Yahong
Li, Wu
author_facet Zhang, Wenjun
Chen, Yanmei
Lei, Tao
Li, Yahong
Li, Wu
author_sort Zhang, Wenjun
collection PubMed
description The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxyl­ate ligands, two O atoms from another two pyridine-2,5-dicarboxyl­ate ligands and two water O atoms. The Pr(III) ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N—H⋯O and O—H⋯O hydrogen bonds are found in the structure.
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spelling pubmed-30892782011-07-13 catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)] Zhang, Wenjun Chen, Yanmei Lei, Tao Li, Yahong Li, Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxyl­ate ligands, two O atoms from another two pyridine-2,5-dicarboxyl­ate ligands and two water O atoms. The Pr(III) ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N—H⋯O and O—H⋯O hydrogen bonds are found in the structure. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089278/ /pubmed/21754299 http://dx.doi.org/10.1107/S1600536811012360 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wenjun
Chen, Yanmei
Lei, Tao
Li, Yahong
Li, Wu
catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
title catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
title_full catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
title_fullStr catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
title_full_unstemmed catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
title_short catena-Poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(III)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
title_sort catena-poly[diimidazolium [bis­(μ-pyridine-2,5-dicarboxyl­ato)bis­[diaqua­praseodymate(iii)]]-bis­(μ-pyridine-2,5-dicarboxyl­ato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089278/
https://www.ncbi.nlm.nih.gov/pubmed/21754299
http://dx.doi.org/10.1107/S1600536811012360
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