rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione

The title compound, C(21)H(23)ClN(2)O(2), was synthesized from N-amino-α-terpinene maleimide and 2-chloro­benzaldehyde. There are two independent mol­ecules in the asymmetric unit which are linked via an inter­molecular C—H⋯O hydrogen bond. The crystal studied was found to be a partial merohedral tw...

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Detalles Bibliográficos
Autores principales: Huang, Jian-Xin, Duan, Wen-Gui, Ma, Xian-Li, Mo, Qi-Jin, Liang, Yin-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089279/
https://www.ncbi.nlm.nih.gov/pubmed/21754542
http://dx.doi.org/10.1107/S1600536811013468
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author Huang, Jian-Xin
Duan, Wen-Gui
Ma, Xian-Li
Mo, Qi-Jin
Liang, Yin-Hua
author_facet Huang, Jian-Xin
Duan, Wen-Gui
Ma, Xian-Li
Mo, Qi-Jin
Liang, Yin-Hua
author_sort Huang, Jian-Xin
collection PubMed
description The title compound, C(21)H(23)ClN(2)O(2), was synthesized from N-amino-α-terpinene maleimide and 2-chloro­benzaldehyde. There are two independent mol­ecules in the asymmetric unit which are linked via an inter­molecular C—H⋯O hydrogen bond. The crystal studied was found to be a partial merohedral twin, with a 0.74 (7):0.26 (7) domain ratio.
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spelling pubmed-30892792011-07-13 rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione Huang, Jian-Xin Duan, Wen-Gui Ma, Xian-Li Mo, Qi-Jin Liang, Yin-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(23)ClN(2)O(2), was synthesized from N-amino-α-terpinene maleimide and 2-chloro­benzaldehyde. There are two independent mol­ecules in the asymmetric unit which are linked via an inter­molecular C—H⋯O hydrogen bond. The crystal studied was found to be a partial merohedral twin, with a 0.74 (7):0.26 (7) domain ratio. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089279/ /pubmed/21754542 http://dx.doi.org/10.1107/S1600536811013468 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Huang, Jian-Xin
Duan, Wen-Gui
Ma, Xian-Li
Mo, Qi-Jin
Liang, Yin-Hua
rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
title rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
title_full rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
title_fullStr rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
title_full_unstemmed rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
title_short rac-(1R,2S,6R,7R)-4-{[(1E)-(2-Chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
title_sort rac-(1r,2s,6r,7r)-4-{[(1e)-(2-chloro­phen­yl)methyl­idene]amino}-1-isopropyl-7-methyl-4-aza­tricyclo­[5.2.2.0(2,6)]undec-8-ene-3,5-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089279/
https://www.ncbi.nlm.nih.gov/pubmed/21754542
http://dx.doi.org/10.1107/S1600536811013468
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