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Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]

In the title complex, [Sn(2)(C(7)H(7))(4)(C(10)H(8)N(2)O(3))(2)(C(2)H(5)OH)(2)], the Sn(IV) atom is seven-coordinated in a distorted penta­gonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl...

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Detalles Bibliográficos
Autores principales: Sun, Shaojun, Yang, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089280/
https://www.ncbi.nlm.nih.gov/pubmed/21754282
http://dx.doi.org/10.1107/S1600536811011937
Descripción
Sumario:In the title complex, [Sn(2)(C(7)H(7))(4)(C(10)H(8)N(2)O(3))(2)(C(2)H(5)OH)(2)], the Sn(IV) atom is seven-coordinated in a distorted penta­gonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, thus forming a dimeric mol­ecule ([Image: see text] symmetry) via weak Sn—O inter­actions. The C atoms of one phenyl ring and the ethanol mol­ecule are disordered over two sets of sites with site-occupancy factors of 0.57 (5):0.43 (5) and 0.79 (2):0.21 (2), respectively. Intermolecular O—H⋯O hydrogen bonds stabilize the crystal structure.